Methyldiphenyl(prop-1-en-2-yl)phosphonium iodide

Base Information

• Chemical Name: Methyldiphenyl(prop-1-en-2-yl)phosphonium iodide
• CAS No.: 30670-21-4
• Molecular Formula: C16H18 P . I
• Molecular Weight: 241.2873
• European Community (EC) Number: 621-730-1
• NSC Number: 123170
• DSSTox Substance ID: DTXSID60451498
• Mol file: 30670-21-4.mol

Synonyms:30670-21-4;Methyldiphenyl(prop-1-en-2-yl)phosphonium iodide;AGN-PC-0NE9GN;DTXSID60451498;NSC123170;AKOS024427470;NSC-123170;Methyldiphenyl(prop-1-en-2-yl)phosphoniumiodide;methyl-diphenyl-prop-1-en-2-ylphosphanium;iodide

Chemical Property of Methyldiphenyl(prop-1-en-2-yl)phosphonium iodide

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 368.01909
• Heavy Atom Count: 18
• Complexity: 239

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC(=C)[P+](C)(C1=CC=CC=C1)C2=CC=CC=C2.[I-]

Technology Process of Methyldiphenyl(prop-1-en-2-yl)phosphonium iodide

There total 3 articles about Methyldiphenyl(prop-1-en-2-yl)phosphonium iodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

dimethyl(oxiran-2-yl)(phenyl)silane (115672-05-4) + diphenylphosphane (829-85-6) + methyl iodide (74-88-4) → diphenylmethyl-2-propenylphosphonium iodide (30670-21-4) + 2-iodoethylidenediphenylmethylphosphorane

Guidance literature:

diphenylphosphane; With n-butyllithium; In tetrahydrofuran; hexane; at 0 ℃; for 0.5h;

dimethyl(oxiran-2-yl)(phenyl)silane; In tetrahydrofuran; hexane; at 20 ℃;

methyl iodide; In tetrahydrofuran; hexane; at 0 - 20 ℃;

DOI:10.1002/chem.200400239

Reference yield:

dimethyl(oxiran-2-yl)(phenyl)silane (115672-05-4) + lithium diphenylphosphide (65567-06-8,4541-02-0) + methyl iodide (74-88-4) → diphenylmethyl-2-propenylphosphonium iodide (30670-21-4) + 2-iodoethylidenediphenylmethylphosphorane

Guidance literature:

Product distribution; different dimethylphenylsilyl- and tert-butyldiphenylsilylepoxides;

DOI:10.1016/S0040-4039(97)10123-X

Reference yield:

→ diphenylmethyl-2-propenylphosphonium iodide (30670-21-4)

Guidance literature:

DOI:10.1039/j39710000343

upstream raw materials:

dimethyl(oxiran-2-yl)(phenyl)silane

lithium diphenylphosphide

methyl iodide

diphenylphosphane