30672-27-6Relevant academic research and scientific papers
Formation of organorhodium complexes via C-H bond activation of 1,3-di(phenylazo)benzene
Majumder, Paramita,Baksi, Suparna,Halder, Sarmistha,Tadesse, Haregewine,Blake, Alexander J.,Drew, Michael G. B.,Bhattacharya, Samaresh
, p. 5423 - 5425 (2011)
Reaction of a potential NCN-pincer ligand, viz. 1,3-di(phenylazo)benzene (L), with [Rh(PPh3)3Cl] affords, via a C-H bond activation, an interesting dinuclear Rh(ii) complex (1), and with RhCl 3·3H2O affords a mononuclear Rh(iii) complex (2) containing a catalytically useful Rh-OH2 fragment. The Royal Society of Chemistry.
