Dalton Transactions p. 5423 - 5425 (2011)
Update date:2022-08-04
Topics:
Majumder, Paramita
Baksi, Suparna
Halder, Sarmistha
Tadesse, Haregewine
Blake, Alexander J.
Drew, Michael G. B.
Bhattacharya, Samaresh
Reaction of a potential NCN-pincer ligand, viz. 1,3-di(phenylazo)benzene (L), with [Rh(PPh3)3Cl] affords, via a C-H bond activation, an interesting dinuclear Rh(ii) complex (1), and with RhCl 3·3H2O affords a mononuclear Rh(iii) complex (2) containing a catalytically useful Rh-OH2 fragment. The Royal Society of Chemistry.
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(1982)