30689-80-6

Basic information

• Product Name: 1-phenyl-c-2-methylcyclohexan-r-1-ol
• CAS NO: 30689-80-6
• Molecular Weight: 190.285
• Mol File: 30689-80-6.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1-phenyl-c-2-methylcyclohexan-r-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 1-phenyl-c-2-methylcyclohexan-r-1-ol(30689-80-6)
• EPA Substance Registry System: 1-phenyl-c-2-methylcyclohexan-r-1-ol(30689-80-6)

Safety Data

• Hazardous Substances Data: 30689-80-6(Hazardous Substances Data)

Upstream product

• 16635-23-7 phenyltriisopropoxytitanium(IV) 
• 583-60-8 2-Methylcyclohexanone 
• 1121-18-2 2-methyl-2-cyclohexen-1-one 
• 35639-05-5 2-methyl-1-phenylcyclohex-2-enol 
• 591-51-5 phenyllithium 
• 101934-18-3 1,5-bis(bromomagnesio)hexane 
• 141-78-6 ethyl acetate 
• 98-80-6 phenylboronic acid 
• 15963-37-8 trans-2-methylcyclohexanol 
• 5123-13-7 5,5-dimethyl-2-phenyl-1,3,2-dioxaborinane 

Relevant articles and documents

Ni-catalysed, domino synthesis of tertiary alcohols from secondary alcohols

The use of in situ generated (NHC)-Ni catalytic species (NHC = N-heterocyclic carbene) allows for the synthesis, in short reaction times, of a variety of tertiary alcohols from secondary alcohols through a domino oxidation-addition protocol.

A Highly Stereoselective Synthesis of Trans-1,2-Disubstituted Cycloalkanols

The study of the reactions of 1,4-bis(bromomagnesio)pentane, 1,1-bis(bromomagnesio)hexane, 1,4-bis(bromomagnesio)heptane, and 1,4-bis(bromomagnesio)octane with aliphatic and aromatic carboxylic acid esters in tetrahydrofuran solution was undertaken in order to ascertain which factors influence isomer distribution.The yields of this annelation processes are in the range of 68-88percent.The formation of trans OH 1,2-disubstituted cyclopentanols having the alkyl groups cis is generally observed with yields of 77-96percent.The reaction of 1,5-bis(bromomagnesio)hexane with carboxylicacid esters is less stereoselective and is more influenced by steric effects.