30719-18-7

Usage

InChI:InChI=1/C4H7IO/c1-3(5)4(2)6/h3H,1-2H3

Upstream product

• 78-93-3 butanone 
• 4091-39-8 3-chloro-2-butanone 
• 814-75-5 3-bromo-butanone 

Downstream Products

• 74676-21-4 4-hydroxy-3-methyl-4-phenyl-2-butanone 
• 81640-13-3 (2R*,3S*)-4-phenyl-4-hydroxy-3-methyl-2-butanone 
• 75600-09-8 (2R*,3R*)-4-phenyl-4-hydroxy-3-methyl-2-butanone 

Relevant academic research and scientific papers

Solid-phase organic synthesis of α-iodo ketones using recyclable resin-bound selenium bromide

A novel facile method for the traceless solid-phase synthesis of α-iodo ketones using a recyclable resin-bound selenium bromide reagent is reported. Various ketones and α-dicarbonyl compounds can be converted to the corresponding α-iodo-substituted compou

Preparation of 1-aminoalkylphosphonic acids and 2-aminoalkylphosphonic acids by reductive amination of oxoalkylphosphonates

By reacting dialkyl 1-oxo- or 2-oxoalkylphosphonates with benzhydrylamine followed by reduction with triacetoxyborohydride and acid hydrolysis gave corresponding aminoalkylphosphonic acids with satisfactory yields. The use of benzylamine, α-methylbenzylamine and tritylamine was unsuccessful in the case of dialkyl 1-oxoalkylphosphonates whereas conversion of 2-oxoalkylphosphonates was also achieved although with lower yields.

Mercury(II) Chloride-Iodine: A Useful Reagent for the Direct and Regiospecific Synthesis of α-Iodocarbonyl Compounds

α-Iodoaldehydes and α-iodoketones are obtained by direct iodination of the corresponding carbonyl compounds with mercury(II) chloride-iodine in a regiospecific manner.

Syntheses de dioxolannes α-iodes

Three methods of iodination of cyclic ketals are described.Direct iodination by monoiodine chloride in ether leads to very good yields in monoiodo compounds.A high selectivity is obtained when one of the α-carbon atoms is tertiary.