308-06-5

Upstream product

• 335-53-5 undecafluorohexanoyl chloride 
• 71-43-2 benzene 
• 434-45-7 2,2,2-Trifluoroacetophenone 
• 423-39-2 1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane 
• 86340-78-5 2,2-difluoro-1-phenyl-1-trimethylsiloxyethene 

Downstream Products

• 65440-93-9 (tridecafluorohexyl)benzene 

Relevant academic research and scientific papers

Photoredox-catalyzed redox-neutral difluoroalkylation to construct perfluoroketones with difluoroenoxysilanes

A mild and facile approach to construct various perfluoroketonesviaphoto-catalyzed difluoroalkylation of difluoroenoxysilanes is developed. The reaction includes a strategy of combination of two fluorine-containing functional groups, which confers the reaction with characteristics like high efficiency, mild conditions, and broad scope. A variety of fluoroalkyl halides including perfluoroalkyl iodides, bromo difluoro esters and amides can be employed as radical precursors. Control experiments indicate that a single-electron transfer pathway may be involved in the reaction.