31040-84-3Relevant articles and documents
Palladium-catalyzed intermolecular C(sp3)-H amidation
Iglesias, Alvaro,Alvarez, Rosana,De-Lera, Angel R.,Muniz, Kilian
supporting information; experimental part, p. 2225 - 2228 (2012/04/10)
Dual capacity: A new palladium-catalyzed intermolecular sequence consisting of the C-H activation and amidation of methyl groups relies on N-fluorobis(phenylsulfonyl)imide (NFSI) as both the oxidant and the nitrogen source. The reaction provides the corresponding arylamines as bissulfonimides along with HF as the only by-product. Both experimental and computational results suggest the involvement of a monomeric palladium(IV) intermediate. Copyright