311-38-6

Basic information

• Product Name: 6,7,13,14-Tetraoxadispiro[4.2.4.2]tetradecane(7CI,8CI,9CI)
• Synonyms: 6,7,13,14-Tetraoxadispiro[4.2.4.2]tetradecane(7CI,8CI,9CI)
• CAS NO: 311-38-6
• Molecular Formula: C₁₀H₁₆O₄
• Molecular Weight: 200.23
• Product Categories: CYCLOPENTANE
• Mol File: 311-38-6.mol
• Article Data: 4

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 6,7,13,14-Tetraoxadispiro[4.2.4.2]tetradecane(7CI,8CI,9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 6,7,13,14-Tetraoxadispiro[4.2.4.2]tetradecane(7CI,8CI,9CI)(311-38-6)
• EPA Substance Registry System: 6,7,13,14-Tetraoxadispiro[4.2.4.2]tetradecane(7CI,8CI,9CI)(311-38-6)

Safety Data

• Hazardous Substances Data: 311-38-6(Hazardous Substances Data)

Upstream product

• 74-87-3 methylene chloride 
• 16189-35-8 bicyclopentylidene 
• 10028-15-6 ozone 
• 120-92-3 cyclopentanone 
• 64-19-7 acetic acid 

Relevant articles and documents

Study of selectivity of metal phosphates and phosphonates in Baeyer-Villiger oxidations

Layered materials including metal phosphates and phosphonates have been widely investigated in several fields acting as good selective catalysts in a great number of oxidative reactions. Zirconium phosphate amorphous [Zr(HPO 4)2?H2O; ZrPA], sodium exchanged zirconium phosphate amorphous [Zr(NaPO4)2; NaZrPA], potassium exchanged zirconium phosphate amorphous [Zr(KPO4)2; KZrPA], zirconium phenylphosphonate amorphous [Zr(O3PC 6H5)2; ZrPPA], zirconium carboxyethylphosphonate [Zr(O3PCH2CH2COOH) 2; ZrCEP] and aluminium carboxyethylphosphonate [Al 3(OH)3(O3PCH2CH2CO 2)2?3H2O; AlCEP] were prepared, characterized and evaluated as selective catalysts in the Baeyer-Villiger oxidation of cyclopentanone, p-methoxybenzaldehyde and 2,4,6- trimethylbenzaldehyde by hydrogen peroxide, in acetic acid. The selectivity of δ-valerolactone, p-methoxyphenol and 2,4,6-trimethylphenol have been found to be strongly related with the properties and structure of each catalyst. Graphical Abstract: The selectivity of zirconium phosphate amorphous [Zr(HPO4)2?H2O; ZrPA], sodium exchanged zirconium phosphate amorphous [Zr(NaPO4)2; NaZrPA], potassium exchanged zirconium phosphate amorphous [Zr(KPO4) 2; KZrPA], zirconium phenylphosphonate amorphous [Zr(O 3PC6H5)2; ZrPPA], zirconium carboxyethylphosphonate [Zr(O3PCH2CH2COOH) 2; ZrCEP] and aluminium carboxyethylphosphonate [Al 3(OH)3(O3PCH2CH2CO 2)2?3H2O; AlCEP] was evaluated in the Baeyer-Villiger oxidation of cyclopentanone, p-methoxybenzaldehyde and 2,4,6-trimethylbenzaldehyde by hydrogen peroxide, in acetic acid. Different selectivities have been found which were correlated with the properties and structure of each compound.

Synthesis and antimalarial activities of novel 3,3,6,6-tetraalkyl-1,2,4,5-tetraoxanes

The oxidative system H2O2/fluorinated alcohol (TFE, HFIP) was used for direct acid- and MeReO3-catalyzed synthesis of 1,2,4,5-tetraoxanes from cyclic (C6, C7, and C12) and acyclic ketones. The influence of ring size and alkyl chain length were studied and antimalarial activities of synthetic 3,3,6,6-tetraalkyl-1,2,4,5-tetraoxanes were determined. Variations in their antimalarial activities were significant, although they share similar electrochemical properties of the peroxide bond.