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Product FOB Price Min.Order Supply Ability Supplier
Diethyl sulfate 64-67-5
Cas No: 64-67-5
No Data No Data No Data Hunan Russell Chemicals Technology Co.,Ltd Contact Supplier
Diethyl sulfate CAS No.: 64-67-5
Cas No: 64-67-5
No Data 1 Kilogram 30 Metric Ton/Day Zouping Sanhao Chemical Co., Ltd . Contact Supplier
Diethyl sulfate
Cas No: 64-67-5
No Data No Data No Data Pure Chemistry Scientific Inc. Contact Supplier

64-67-5 Usage

General Description

A clear colorless liquid with a peppermint odor. Burns, though may be difficult to ignite. Corrosive to metals and tissue.

Carcinogenicity

Diethyl sulfate is reasonably anticipated to be a human carcinogenbased on sufficient evidence of carcinogenicity from studies in experimental animals.

Uses

The primary use of diethyl sulfate is as a chemical intermediate (ethylating agent) in synthesis of ethyl derivatives of phenols, amines, and thiols; as an accelerator in the sulfation of ethylene; and in some sulfonation processes. It is used to manufacture dyes, pigments, carbonless paper, and textiles. It is an intermediate in the indirect hydration (strong acid) process for the preparation of synthetic ethanol from ethylene. Smaller quantities are used in household products, cosmetics, agricultural chemicals, pharmaceuticals, and laboratory reagents (IARC 1992, 1999, HSDB 2009). In 1966, it was used as a mutagen to create the Luther variety of barley (IARC 1974).

Uses

As an ethylating agent; as an accelerator in the sulfation of ethylene; intermediate in the production by one method of ethyl alcohol from ethylene and sulfuric acid

Chemical Properties

Diethyl sulfate is a colorless, oily liquid with a faint peppermint- like odor, which darkens with age (Budavari, 1996). It is miscible with alcohol and ether (O'Neil, 2006). At higher temperatures, DES rapidly decomposes into monoethyl sulfate and alcohol (NTP, 2011).

Health Hazard

May be fatal if inhaled, swallowed or absorbed through skin. Inhalation causes nausea and vomiting. Causes burns to skin and eyes. Ingestion may cause nausea, vomiting abdominal pain and collapse.

Purification Methods

Wash the ester with aqueous 3% Na2CO3 (to remove acidic material), then distilled water, dry (CaCl2), filter and distil it in a vacuum. It is an ethylating agent and blisters the skin. [Beilstein 1 IV 1236.]

Air & Water Reactions

Highly flammable. Slowly reacts with water to form ethyl alcohol, a flammable liquid, and ethyl sulfate, with eventual conversion to sulfuric acid.

Preparation

Diethyl sulfate is produced from ethanol and sulfuric acid, from ethylene and sulfuric acid, or from diethyl ether and fuming sulfuric acid (Budavari, 1996).

Safety Profile

Confirmed carcinogen with experimental carcinogenic and tumorigenic data. Poison by inhalation and subcutaneous routes. Moderately toxic by ingestion and sktn contact. A severe skin irritant. An experimental teratogen. Mutation data reported. Combustible when exposed to heat or flame; can react with oxidzing materials. Moisture causes liberation of H2SO4. Violent reaction with potassium tert-butoxide. Reacts violently with 3,8-dnitro-6-phenylphenanthridine + water. Reaction with iron + water forms explosive hydrogen gas. To fight fire, use alcohol foam, H2O foam, CO2, dry chemicals. When heated to decomposition it emits toxic fumes of SOx. See also SULFATES.

Reactivity Profile

The presence of moisture in a metal container of Diethyl sulfate caused the formation of sulfuric acid which reacts with the metal to release hydrogen which pressurized and exploded the container [Chem. Abst. 28:2908(1934)].
InChI:InChI=1/C4H10.H2O4S/c1-3-4-2;1-5(2,3)4/h3-4H2,1-2H3;(H2,1,2,3,4)/p-2

64-67-5 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
TCI America (D0525)  Diethyl Sulfate  >98.0%(GC) 64-67-5 25mL 150.00CNY Detail
TCI America (D0525)  Diethyl Sulfate  >98.0%(GC) 64-67-5 500mL 250.00CNY Detail
Alfa Aesar (L14291)  Diethyl sulfate, 98%    64-67-5 100ml 179.0CNY Detail
Alfa Aesar (L14291)  Diethyl sulfate, 98%    64-67-5 500ml 372.0CNY Detail
Aldrich (D100706)  Diethylsulfate  98% 64-67-5 D100706-100G 430.56CNY Detail
Aldrich (D100706)  Diethylsulfate  98% 64-67-5 D100706-1KG 558.09CNY Detail
Aldrich (D100706)  Diethylsulfate  98% 64-67-5 D100706-2KG 902.07CNY Detail

64-67-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name Diethyl sulfate

1.2 Other means of identification

Product number -
Other names Ethylsulpate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Diethyl sulfate is primarily used as an ethylating agent, and also as an accelerator in the sulfation of ethylene and in some sulfonations. Diethyl sulfate is also a chemical intermediate for ethyl derivatives of phenols, amines, and thiols, and as an alkylating agent.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:64-67-5 SDS

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