313220-01-8Relevant academic research and scientific papers
Intramolecular B/N frustrated Lewis pairs and the hydrogenation of carbon dioxide
Courtemanche, Marc-André,Pulis, Alexander P.,Rochette, étienne,Légaré, Marc-André,Stephan, Douglas W.,Fontaine, Frédéric-Georges
, p. 9797 - 9800 (2015)
The FLP species 1-BR2-2-NMe2-C6H4 (R = 2,4,6-Me3C6H21, 2,4,5-Me3C6H22) reacts with H2 in sequential hydrogen activation and protodeborylation reactions to give (1-BH2-2-NMe2-C6H4)23. While 1 reacts with H2/CO2 to give formyl, acetal and methoxy-derivatives, 2 reacts with H2/CO2 to give C6H4(NMe2)(B(2,4,5-Me3C6H2)O)2CH24. The mechanism of CO2 reduction is considered.
Synthesis and properties of fluorescent organoboranes: Triarylmethane-type dyes
Albrecht, Karsten,Kaiser, Volker,Boese, Roland,Adams, Joerg,Kaufmann, Dieter E.
, p. 2153 - 2157 (2007/10/03)
The syntheses and photochemical properties of the novel aminoaryldiarylboranes, 4, which are isoelectronic with triarylmethane dyes, and also pyrrolyl-8, and indolyl-diarylboranes 11, are described. The fluorescence spectra are strongly dependent on the s
