Chemical Communications p. 9797 - 9800 (2015)
Update date:2022-07-29
Topics: Selectivity Hydrogenation High Reactivity Mild conditions
Courtemanche, Marc-André
Pulis, Alexander P.
Rochette, étienne
Légaré, Marc-André
Stephan, Douglas W.
Fontaine, Frédéric-Georges
The FLP species 1-BR2-2-NMe2-C6H4 (R = 2,4,6-Me3C6H21, 2,4,5-Me3C6H22) reacts with H2 in sequential hydrogen activation and protodeborylation reactions to give (1-BH2-2-NMe2-C6H4)23. While 1 reacts with H2/CO2 to give formyl, acetal and methoxy-derivatives, 2 reacts with H2/CO2 to give C6H4(NMe2)(B(2,4,5-Me3C6H2)O)2CH24. The mechanism of CO2 reduction is considered.
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