313374-39-9

Basic information

• Product Name: Zinc, ethylphenyl-
• CAS NO: 313374-39-9
• Molecular Formula: C8H10Zn
• Molecular Weight: 171.557
• Mol File: 313374-39-9.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Zinc, ethylphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Zinc, ethylphenyl-(313374-39-9)
• EPA Substance Registry System: Zinc, ethylphenyl-(313374-39-9)

Safety Data

• Hazardous Substances Data: 313374-39-9(Hazardous Substances Data)

Upstream product

• 3262-89-3 triphenylboroxine 
• 557-20-0 diethylzinc 
• 1078-58-6 diphenylzinc 
• 925-90-6 ethylmagnesium bromide 
• 100-58-3 phenylmagnesium bromide 
• 7646-85-7 zinc(II) chloride 
• 98-80-6 phenylboronic acid 
• 109-72-8 n-butyllithium 
• 2633-75-2 ethylzinc chloride 

Downstream Products

• 99412-45-0 (S)-naphthalen-2-yl(phenyl)methanol 
• 130912-38-8 (2S,3S,4R,5R,6R)-4,5-bis(benzyloxy)-6-((benzyloxy)methyl)-2-phenyltetrahydro-2H-pyran-3-ol 
• 20672-66-6 3,4,6-tri-O-benzyl-D-glucopyranose 
• 5398-11-8 3‐phenylisobenzofuran‐1(3H)‐one 
• 5398-11-8 (S)-3-phenyl-1,3-dihydro-2-benzofuran-1-one 
• 54963-91-6 (R)-1-phenyl-1,2,3,4-tetrahydronaphthalen-1-ol 
• 57018-60-7 (+)-(S)-1-phenyl-1,2,3,4-tetrahydronaphthalen-1-ol 
• 245432-28-4 (R)-(2-bromophenyl)(phenyl)methanol 
• 80441-37-8 2-phenyloctan-2-ol 
• 123436-08-8 (S)-(2-methoxyphenyl)phenylmethanol 
• 40412-38-2 (R)-1-cyclohexyl-1-phenylethan-1-ol 
• 19490-92-7 1-phenyl-1-(pyridin-2-yl)ethanol 

Relevant articles and documents

Catalytic asymmetric 1,2-Addition/Lactonization tandem reactions for the syntheses of chiral 3-Substituted phthalides using organozinc reagents

Using chiral phosphoramide ligand 2d-Zn (II) complex derived from (1R,2R)-1,2-diphenylethylenediamine as the catalyst, we have developed efficient catalytic asymmetric 1,2-addition/lactonization tandem reactions of diverse organozinc reagents with varied methyl 2-formylbenzoates for the construction of optically enriched 3-aryl or alkyl substituted phthalides, which are significant building blocks of many important chiral pharmaceuticals and natural products. The corresponding products could be afforded with good to excellent yields (up to 95%) and moderate to good enantioselectivities (up to 89%).

Zn(salen)-catalyzed enantioselective phenyl transfer to aldehydes and ketones with organozinc reagent

Abstract A chiral zinc complex of salen was found to be an efficient catalyst for the phenyl transfer of organozinc reagent to aromatic aldehydes and ketones. High enantioselectivities were obtained in reactions of both aromatic aldehydes and ketones (up to 97% and 92% ee, respectively).

Practical catalytic asymmetric synthesis of diaryl-, aryl heteroaryl-, and diheteroarylmethanols

Enantioenriched diaryl-, aryl heteroaryl-, and diheteroarylmethanols exhibit important biological and medicinal properties. One-pot catalytic asymmetric syntheses of these compounds beginning from readily available aryl bromides are introduced. Thus, lith