31367-69-8

Basic information

• Product Name: Benzenethiol, 4-methyl-, potassium salt
• CAS NO: 31367-69-8
• Molecular Formula: C7H8S.K
• Molecular Weight: 162.297
• Mol File: 31367-69-8.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Benzenethiol, 4-methyl-, potassium salt(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenethiol, 4-methyl-, potassium salt(31367-69-8)
• EPA Substance Registry System: Benzenethiol, 4-methyl-, potassium salt(31367-69-8)

Safety Data

• Hazardous Substances Data: 31367-69-8(Hazardous Substances Data)

Upstream product

• 20114-05-0 2,4-dinitrobenzene p-methylbenzene sulfide 
• 106-45-6 para-thiocresol 
• 103-19-5 di(p-tolyl) disulfide 
• 68960-59-8 racemic 4-p-tolylthio-2-azetidinone 

Downstream Products

• 54091-17-7 3-(p-tolylthio)butan-2-one 
• 352-68-1 4-trifluoromethylthiotoluene 
• 96568-24-0 2-chloro-5-fluoro-6-(p-tolylthio)nicotinonitrile 
• 313053-67-7 Ni(C₆F₅)[(C₆H₅)2PCH₂]2(SC₆H₄CH₃) 
• 311819-16-6 (CH₃C₆H₄)3Zn^(1-)*K⁽¹⁺⁾=(CH₃C₆H₄)3ZnK 
• 313053-54-2 Ni(C₆F₅)[P(C₆H₅)2CH₃]2(SC₆H₄CH₃) 
• 208454-98-2 ((CH₃)5C₅)Pt(CH₃)2(SC₆H₄CH₃) 
• 412339-56-1 3-phenyl-3-(p-tolylthio)propanoic acid 
• 1244670-52-7 (C₅Me₅)2U(S-p-tolyl)2 
• 1110648-16-2 Ni(N,N'-diethyl-3,7-diazanonane-1,9-dithiolate)Ni(S-p-Tol)2 
• 173202-98-7 [(η(5)-C5Me5)(PMe3)Ir(CH2C(O)CH3)(S-p-tolyl)] 
• 173203-28-6 [(η(5)-C5Me5)(PMe3)Ir(S-p-tolyl)2] 
• 343881-15-2 [palladium(II)-(pentafluorophenyl)(p-SC₆H₄CH₃)(o-(Ph₂P)C₆H₄-CH=N-i-Pr)] 
• 92476-41-0 (CH₃CH₂)3Zn^(1-)*K⁽¹⁺⁾=(CH₃CH₂)3ZnK 

Relevant articles and documents

Potassium isopropoxide: For sulfination it is the only base you need!

PEPPSI max: KOiPr has been identified as the key ingredient for Pd-catalyzed sulfination (see scheme). Potassium is essential to keep the thiol concentration low, and isopropoxide is necessary for precatalyst activation and to break up Pd-sufide-based resting states. Together with the reactive Pd-PEPPSI-IPentCl o-picoline catalyst, this system couples profoundly deactivated partners at RT that other catalysts cannot accomplish in refluxing toluene. Copyright

Base-Catalyzed Elimination of Para-Substituted Thiophenoxides from 4-(Arylthio)azetidin-2-ones

-

Process for preparing 2-amino-5-nitrophenol derivatives

A process for efficiently preparing 2-amino-5-nitrophenol derivatives in which benzoxazole derivatives are subjected to nucleophilic substitution reaction at the 5 position thereof to obtain corresponding benzoxazole derivatives, and the oxazole ring of the benzoxazole derivatives is then subjected to ring-opening to obtain 2-amino-5-nitrophenol derivatives. The 2-amino-5-nitrophenol derivatives are useful as industrial starting materials, reducing agents or antioxidants and intermediates for cyan-image-forming couplers.