313695-94-2

Basic information

• Product Name: (4S,5S)-1-tert-butoxycarbonyl-4,5-diphenyl-2-[(R)-1-(1-naphthyl)ethylimino]imidazolidine
• Synonyms: (4S,5S)-1-tert-butoxycarbonyl-4,5-diphenyl-2-[(R)-1-(1-naphthyl)ethylimino]imidazolidine
• CAS NO: 313695-94-2
• Molecular Weight: 491.633
• Mol File: 313695-94-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (4S,5S)-1-tert-butoxycarbonyl-4,5-diphenyl-2-[(R)-1-(1-naphthyl)ethylimino]imidazolidine(CAS DataBase Reference)
• NIST Chemistry Reference: (4S,5S)-1-tert-butoxycarbonyl-4,5-diphenyl-2-[(R)-1-(1-naphthyl)ethylimino]imidazolidine(313695-94-2)
• EPA Substance Registry System: (4S,5S)-1-tert-butoxycarbonyl-4,5-diphenyl-2-[(R)-1-(1-naphthyl)ethylimino]imidazolidine(313695-94-2)

Safety Data

• Hazardous Substances Data: 313695-94-2(Hazardous Substances Data)

Upstream product

• 29841-69-8 (S,S)-1,2-diphenyl-1,2-diaminoethane 
• 3886-70-2 (R)-1-(1-Naphthyl)ethylamine 
• 313695-70-4 N-[(1S,2S)-2-amino-1,2-diphenylethyl]-N'-[(R)-1-(1-naphthyl)ethyl]thiourea 
• 313695-81-7 N-[(1S,2S)-2-tert-butoxycarbonylamino-1,2-diphenylethyl]-N'-[(R)-1-(1-naphthyl)ethyl]thiourea 
• 138617-82-0 (R)-[1-(1-naphthyl)ethyl] isothiocyanate 

Relevant articles and documents

Modified guanidines as potential chiral superbases. 2. Preparation of 1,3-unsubstituted and 1-substituted 2-iminoimidazolidine derivatives and a related guanidine by the 2-chloro-1,3-dimethylimidazolinium chloride-induced cyclization of thioureas

Simple preparation methods for modified guanidines were explored for new chiral superbases. Thus, (4S,5S)-4,5-diphenyl- and diastereomeric cyclohexane-fused 2-iminoimidazolidines were prepared from (1S,2S) - 1,2 -diphenylethylenediamine and (1R,2R)- or (1S,2S)-1,2-diaminocyclohexanes through cyclization of protected thiourea intermediates with 2-chloro-1,3-dimethylimidazolinium chloride (DMC) as a key reaction. In the (4S,5S)-4,5-diphenyl series 1-methyl-2-iminoimidazolidines and 2-diethylaminoimidazoline were also prepared as related guanidines.