3142-78-7Relevant articles and documents
Comparison of gas-phase acidities of some carbon acids with their rates of hydron exchange in methanolic methoxide
DeTuri, Vincent F.,Koch, Heinz F.,Koch, Judith G.,Lodder, Gerrit,Mishima, Masaaki,Zuilhof, Han,Abrams, Neal M.,Anders, Cecily E.,Biffinger, Justin C.,Han, Patrick,Kurland, Adam R.,Nichols, Jason M.,Ruminski, Anne M.,Smith, Patricia R.,Vasey, Karen D.
, p. 308 - 317 (2007/10/03)
Hydron exchange reaction rates, kexch M-1s -1, using methanolic sodium methoxide are compared with gas-phase acidities, ΔGAcid0 kcal/mol, for four 9-YPhenylfluorenes-9-iH, seven YC6/s
Synthesis of 2-phenylperfluoropropene and 1,1,1,3,3,3-hexafluoro-2-phenylpropane
Bhadury, Pinaki S.,Pant, Bhagwat P.,Palit, Meehir,Jaiswal, Devendra K.
, p. 115 - 116 (2007/10/03)
We describe the optimisation of reaction conditions for the synthesis of 2-phenylperfluoropropene and its HF addition product 1,1,1,3,3,3-hexafluoro-2-phenylpropane from 1,1,1-trifluoroacetophenone by the reaction with sodium chlorodifluoroacetate and tri
Proton-Transfer Reactions. 4. Near-Unity Kinetic Isotope Effects for Hydron Exchange and Dehydrofluorination Reactions
Koch, Heinz F.,Dahlberg, Donald B.,Lodder, Gerrit,Root, Karen S.,Touchette, Nancy A.,et al.
, p. 2394 - 2398 (2007/10/02)
Rates and isotope effects are reported for benzylic hydron exchange and dehydrofluorination reactions of C6H5CiHClCF3 (I) and C6H5CiH(CF3)2 (II) in alcoholic sodium alkoxide solutions.Reactions of I were studied in ethanol and isotop
