378-34-7

Usage

Uses

Used in Electronics Industry:
HEPTAFLUOROISOPROPYLBENZENE 98 is used as a solvent for the manufacturing of electronic components due to its high chemical stability and electrical resistance, which are crucial for the production of advanced materials and electronic devices.
Used in Specialty Polymers Industry:
In the specialty polymers industry, HEPTAFLUOROISOPROPYLBENZENE 98 is utilized as a solvent for the synthesis of unique polymers that can withstand extreme conditions, capitalizing on its high thermal stability and chemical inertness.
Used in Chemical Synthesis:
HEPTAFLUOROISOPROPYLBENZENE 98 serves as a solvent in chemical synthesis processes, where its low toxicity and high purity contribute to the creation of high-quality end products in a controlled environment.

InChI:InChI=1/C9H5F7/c10-7(8(11,12)13,9(14,15)16)6-4-2-1-3-5-6/h1-5H

Upstream product

• 591-50-4 iodobenzene 
• 677-69-0 perfluoroisopropyl iodide 
• 116-15-4 perfluoropropylene 
• 98-80-6 phenylboronic acid 
• 71-43-2 benzene 
• 718-64-9 1,1,1,3,3,3-hexafluoro-2-phenylisopropyl alcohol 

Downstream Products

• 1979-51-7 1,1,3,3,3-pentafluoro-2-phenylpropene 
• 3142-78-7 1,1,1,3,3,3-hexafluoro-2-phenylpropane 
• 2396-18-1 m-(Heptafluorisopropyl)-N,N-dimethylanilin 
• 2396-16-9 3-iso-C₃F₇C₆H₄NH₂ 
• 2396-20-5 m-(Heptafluorisopropyl)-benzoesaeure 
• 2396-24-9 m-Fluor-(heptafluorisopropyl)-benzol 
• 2396-22-7 1-bromo-3-heptafluoroisopropylbenzene 
• 2396-13-6 1-nitro-3-(perfluoropropan-2-yl)benzene 
• 2021-68-3 perfluoroisopropylcyclohexane 

Relevant academic research and scientific papers

METHOD FOR PREPARATION OF FLUORO ALKYLATED COMPOUNDS BY HOMOGENEOUS NI CATALYSIS

The invention discloses a method for the preparation of fluoro alkylated compounds by homogeneous Ni catalyzed fluoro alkylation with fluoro alkyl halides in the presence of a base.

A hexafluoropropylene directly to the aryl borate method of oxidation heptafluoro isopropylation

The invention relates to a method for directly oxidizing arylboronic acid into heptafluoroisopropyl by utilizing hexafluoropropylene. The method comprises the following steps that silver fluoride is used as a fluorine source, under the effect of copper salt, the hexafluoropropylene and the arylboronic acid can be converted into a series of compounds containing heptafluoroisopropyl in organic solvents at the room temperature, and the reaction is also applicable to alkenylboronic acids. The method has the advantage that a series of compounds containing the heptafluoroisopropyl are synthesized through one-step reaction at high selectivity.

Copper-mediated aerobic iodination and perfluoroalkylation of boronic acids with (CF3)2CFI at room temperature

The copper-mediated aerobic reactions between the branched (CF3)2CFI and boronic acids (R-B(OH)2) are described. Different from the linear perfluoroalkyl analogs CF3(CF2)nI (n?=?2, 3, 5, 7), (CF3)2CFI reacting with R-B(OH)2at room temperature under air in the presence of catalytic Cu powder provided exclusively the corresponding iodides (R-I), while the aerobic reactions of arylboronic acids with (CF3)2CFI at room temperature in the presence of Cu(OAc)2gave the perfluoroalkylation products (R-CF(CF3)2) in acceptable to moderate yields. The iodination reaction could be further promoted by hydroquinone, the addition of which improved the oxidation ability of (CF3)2CFI and provided the ipso-iodination products in high yields. The perfluoroalkylation was facilitated by the copper carboxylates since the addition of these salts into the reaction mixtures could successfully give rise to Ar-CF(CF3)2.

Direct heptafluoroisopropylation of arylboronic acids via hexafluoropropene (HFP)

A novel and straightforward strategy for heptafluoroisopropylation of arylboronic acids at room temperature has been developed. This method, directly using commercial available hexafluoropropene (HFP) as the starting material, provides a new way to synthesize a variety of synthetically useful heptafluoroisopropylated arenes.

Syntheses of lipophilic tetraarylborate ions substituted with many perfluoroalkyl groups and their stability under acid conditions

Syntheses are investigated on several new kinds of perfluoroalkyl-substituted tetraarylborate ions such as tetrakis(3,5-bis(nonafluorobutyl)phenyl)borate, tetrakis(3,5-bis(heptafluoro-2-propyl)phenyl)borate (PFPB), tetrakis(3-(heptafluoro-2-propyl)-1-(tri

PALLADIUM-CATALYZED CROSS-COUPLING REACTIONS BETWEEN ALLYL, VINYL OR ARYL HALIDE AND PERFLUOROALKYL IODIDE WITH ZINC AND ULTRASONIC IRRADIATION

The reactions of perfluoroalkyl iodides with allyl, vinyl or aryl halides with ultrasonically dispersed zinc in the presence of palladium catalyst proceeded smoothly to give the corresponding allyl, vinyl or aryl perfluoroalkylides in a good yield.