31444-36-7Relevant academic research and scientific papers
Alkyl-alkyl Suzuki cross-couplings of unactivated secondary alkyl halides at room temperature
Saito, Bunnai,Fu, Gregory C.
, p. 9602 - 9603 (2007)
A commercially available 1,2-diamine serves as an effective ligand for metal-catalyzed cross-couplings of unactivated alkyl electrophiles at room temperature. In particular, Ni/trans-N,N′-dimethyl-1,2-cyclohexanediamine provides the first method for achie
Enantioselective alkyl-alkyl suzuki cross-couplings of unactivated homobenzylic halides
Saito, Bunnai,Fu, Gregory C.
, p. 6694 - 6695 (2008/12/22)
The first effective method for asymmetric cross-couplings of unactivated alkyl electrophiles has been developed, specifically, a nickel-based catalyst for stereoconvergent Suzuki reactions of homobenzylic bromides with alkylboranes. To the best of our knowledge, there are no previous examples of enantioselective Suzuki couplings of alkyl electrophiles (activated or unactivated). Both of the catalyst components are commercially available. Copyright
Preparation and Thermal Isomerization of β-Arylthio α,β-Unsaturated Thioketone Dimer
Karakasa, Takayuki,Satsumabayashi, Sadayoshi,Motoki, Shinichi
, p. 335 - 337 (2007/10/02)
β-Arylthio α,β-unsaturated thioketone dimer, 3,6-diphenyl-4-arylthio-3--3,4-dihydro-1,2-dithiin, has been prepared.Thermal isomerization of 3,4-dihydro-1,2-dithiin (aryl=phenyl) afforded 6-phenyl-2,4-bis(phenylthio)-3-thiobenzoyl-3,4-
