31463-30-6

Basic information

• Product Name: N-[(3s,5s,7s)-adamantan-1-yl]-N-phenylhydroxylamine
• Synonyms: N-[(3s,5s,7s)-adamantan-1-yl]-N-phenylhydroxylamine
• CAS NO: 31463-30-6
• Molecular Weight: 243.349
• Mol File: 31463-30-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-[(3s,5s,7s)-adamantan-1-yl]-N-phenylhydroxylamine(CAS DataBase Reference)
• NIST Chemistry Reference: N-[(3s,5s,7s)-adamantan-1-yl]-N-phenylhydroxylamine(31463-30-6)
• EPA Substance Registry System: N-[(3s,5s,7s)-adamantan-1-yl]-N-phenylhydroxylamine(31463-30-6)

Safety Data

• Hazardous Substances Data: 31463-30-6(Hazardous Substances Data)

Upstream product

• 828-51-3 1-Adamantanecarboxylic acid 
• 586-96-9 Nitrosobenzene 
• 768-94-5 1-Adamantanamine 
• 22734-10-7 1-Nitrosoadamantane 
• 31463-23-7 N-adamantylhydroxylamine 

Relevant articles and documents

Photoredox Synthesis of Arylhydroxylamines from Carboxylic Acids and Nitrosoarenes

Hydroxylamines are found in biologically active compounds and serve as building blocks for the preparation of nitrogen-containing molecules. Here the direct conversion of carboxylic acids into the corresponding alkylhydroxylamines using organo-photoredox catalysis is reported. The process relies in the generation of alkyl radicals via photoinduced oxidation-decarboxylation and their following reaction with nitrosoarenes. We have successfully applied this method to the late-stage modification of complex and biologically active acids and applied it in novel radical cascade processes.