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22734-10-7

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22734-10-7 Usage

General Description

1-Nitrosoadamantane, also known as N-Adamantyl nitrosamine, is a chemical compound with the molecular formula C10H16N2O. It is a stable organic nitroso compound that is commonly used in organic synthesis and as a building block for various chemical reactions. 1-Nitrosoadamantane has been studied for its potential applications in pharmaceuticals, agriculture, and material science. It has also been investigated for its role as a catalyst in various chemical reactions. Additionally, it has shown potential as a radical scavenger and antioxidant, which could have implications for its use in medical and pharmaceutical applications. The chemical structure of 1-nitrosoadamantane incorporates both nitroso and adamantane moieties, which gives it unique properties and potential applications in various areas of research and industry.

Check Digit Verification of cas no

The CAS Registry Mumber 22734-10-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 2,2,7,3 and 4 respectively; the second part has 2 digits, 1 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 22734-10:
(7*2)+(6*2)+(5*7)+(4*3)+(3*4)+(2*1)+(1*0)=87
87 % 10 = 7
So 22734-10-7 is a valid CAS Registry Number.
InChI:InChI=1/C10H15NO/c12-11-10-4-7-1-8(5-10)3-9(2-7)6-10/h7-9H,1-6H2

22734-10-7Relevant articles and documents

SYNTHESIS OF DI-t-ALKYLAMINES

Corey, E. J.,Gross, Andrew W.

, p. 491 - 494 (1984)

Di-t-alkylamines can be synthesized efficiently by a three-step process: (1) oxidation of a t-alkylamine to a t-alkylnitroso compound with peracetic acid in ethyl acetate (2) conversion of the t-alkylnitroso compound to a tri-t-alkylhydroxylamine by successive trapping of two t-butyl radicals and (3) sodium naphthalide reduction to the di-t-alkylamine.

Chemoselectivity of Nitroxylation of Cage Hydrocarbons

Ivleva, E. A.,Klimochkin, Yu. N.,Leonova, M. V.

, p. 1702 - 1710 (2020/12/01)

Abstract: The composition of reaction mixtures obtained by nitroxylation of 13 cage hydrocarbons with 100% nitric acid and its mixtures with acetic acid, acetic anhydride, and methylene chloride has been studied. More reactive substrates react with lowest

Azodioxide radical cations

Greer, Melinda L.,Sarker, Haripada,Mendicino, Maria E.,Blackstock, Silas C.

, p. 10460 - 10467 (2007/10/03)

This report provides the first examples of solution-stable azodioxide radical cations and describes their direct spectroscopic observation and, in one case, their thermal chemistry. The formal oxidation potentials, Eo′, for N,N′-dioxo-2,3-diazabicyclo[2.2.2]oct-2-ene (3), N,N′-dioxo-2,3-diazabicyclo[2.2.1]hept-2-ene (4), and N,N′-dioxo-1,1′-azobis(norbornane) (5) are 1.65, 1.68, and 1.54 V vs SCE, respectively. ESR spectroscopy shows the intermediate cations to be π radicals. Radical cation 5?+ (red, λm 510 nm) has a five-line ESR spectrum of a(2N) 1.1 G, while 3?+ (bronze) has a nine-line ESR spectrum simulated as a(4H) 0.86 and a(2N) 1.22 G. Both 3?+ and 5?+ decay in seconds to minutes at room temperature. Thermal decomposition of 5?+ results in C,N and N,N bond cleavage, yielding 1-norbornyl cation (trapped by solvent) and NO+ (trapped in low yield by the oxidant under chemical oxidation conditions). Two viable mechanisms are presented for 5?+'s thermal decay, both of which invoke nitrosoalkane monomer 5m as an intermediate. In a related study, oxidation of nitrosoalkane 2m is found to mediate its facile denitrosation. This work affords the first examples of electron-transfer-mediated C,N bond cleavage of azodioxides and of nitrosoalkanes. Substantial bond weakening is shown to accompany electron loss from these substrates. For 5, π oxidation leads ultimately to σ C,N bond activation.

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