314733-83-0

Upstream product

• 204203-16-7 2,6-bis(1-(2,6-dimethylphenylimino)ethyl)pyridine 
• 52462-29-0 [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 
• 74-85-1 ethene 

Downstream Products

• 314733-85-2 (C₆H₃(CH₃)2NCCH₃)2C₅H₃NRuCl(C₂H₄)2⁽¹⁺⁾*B(C₆H₃(CF₃)2)4^(1-)=(C₆H₃(CH₃)2NCCH₃)2C₅H₃NRuCl(C₂H₄)2*B(C₆H₃(CF₃)2)4 
• 1207614-52-5 [κ2-2,6-(2,6-Me2C6H3NCMe)2pyridyl]Ru(η6-toluene) 
• 1207614-55-8 [2,6-(2,6-Me₂C₆H₃NCMe)2pyridyl]Ru(H)(Cl)(ethylene) 
• 1207614-51-4 trans-[2,6-(2,6-Me₂C₆H₃NCMe)2pyridyl]RuCl₂(CO) 

Relevant academic research and scientific papers

Stable, cationic alkyl-olefin complexes of ruthenium(II) and rhodium(III): effects of ligand geometry upon olefin insertion/alkyl migration

The syntheses of ruthenium(II) and rhodium(III) model complexes of the putative active species in the iron(II)/MMAO polymerization system are reported. The cationic ruthenium methyl ethylene complex 3 is a stable, isolable compound, which does not produce polyethylene under a variety of conditions. Likewise, the analogous rhodium complex 12 shows no appreciable polymerization activity, despite its similarity to existing rhodium complexes which are active catalysts for olefin polymerization. X-ray crystal structures of the cationic ruthenium bis(ethylene) complex 7 and the five-coordinate rhodium bis(triflate) methyl complex 9 are also presented.