[2,6-(2,6-Me₂C₆H₃NCMe)2pyridyl]RuCl₂(ethylene)

Base Information

Chemical Name:[2,6-(2,6-Me₂C₆H₃NCMe)2pyridyl]RuCl₂(ethylene)
CAS No.:314733-83-0
Molecular Formula:C₂₇H₃₁Cl₂N₃Ru
Molecular Weight:569.539
Hs Code.:

[2,6-(2,6-Me<sub>2</sub>C<sub>6</sub>H<sub>3</sub>NCMe)2pyridyl]RuCl<sub>2</sub>(ethylene)

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Chemical Property of [2,6-(2,6-Me₂C₆H₃NCMe)2pyridyl]RuCl₂(ethylene)

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Technology Process of [2,6-(2,6-Me₂C₆H₃NCMe)2pyridyl]RuCl₂(ethylene)

There total 1 articles about [2,6-(2,6-Me₂C₆H₃NCMe)2pyridyl]RuCl₂(ethylene) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 204203-16-7
2,6-bis(1-(2,6-dimethylphenylimino)ethyl)pyridine

: 52462-29-0
[ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂

: 74-85-1
ethene

: 314733-83-0
[2,6-(2,6-Me₂C₆H₃NCMe)2pyridyl]RuCl₂(ethylene)

Guidance literature:: In ethanol; a soln. of 1 equiv of complex and 2 equiv of pyridine-compound in abs. ethanol was refluxed under etylene atm. for 12 h, cooled to room temp.; ppt. was filtered, dried overnight in vac., extd. with CH2Cl2, concd.;
DOI:10.1021/om000674i

Reference yield: 86.0%

: 74-85-1
ethene

: 314733-83-0
[2,6-(2,6-Me₂C₆H₃NCMe)2pyridyl]RuCl₂(ethylene)

: 79060-88-1
sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate

: 314733-85-2
(C₆H₃(CH₃)2NCCH₃)2C₅H₃NRuCl(C₂H₄)2⁽¹⁺⁾*B(C₆H₃(CF₃)2)4^(1-)=(C₆H₃(CH₃)2NCCH₃)2C₅H₃NRuCl(C₂H₄)2*B(C₆H₃(CF₃)2)4

Guidance literature:: In dichloromethane; byproducts: NaCl; the mixt. in Ch2Cl2 was stirred at room temp. for 2.5 h under C2H4 atm.; filtered, NaCl was washed with CH2Cl2, the combuned fractions were dried in vac., the solid was dissolved in CH2Cl2 under Ar, pentane was added, the mixt. was stirred, cooled to 0°C, filtered; elem. anal.;
DOI:10.1021/om000674i

Reference yield: 83.0%

: 314733-83-0
[2,6-(2,6-Me₂C₆H₃NCMe)2pyridyl]RuCl₂(ethylene)

: 201230-82-2
carbon monoxide

: 1207614-51-4
trans-[2,6-(2,6-Me₂C₆H₃NCMe)2pyridyl]RuCl₂(CO)

Guidance literature:: In CH₂Cl₂; byproducts: ethylene; CH2Cl2 soln. of Ru complex stirred under CO (1 atm) at room temp. for 45min; volatiles removed in vac.; washed with benzene; filtered in air;
DOI:10.1021/om9009075