31481-55-7Relevant academic research and scientific papers
Computer-Assisted Design of Chiral Boron Enolates: The Role of Ate Complexes in Determining Aldol Stereoselectivity.
Bernardi, Anna,Comotti, Angiolina,Gennari, Cesare,Hewkin, Cheryl T.,Goodman, Jonathan M.,et al.
, p. 1227 - 1242 (1994)
Transition-state modelling for the aldol reaction of chiral Z and E enol borinates (1 and 2, Scheme 1) bearing mixed ligands (L1=Ipc, L2=9) predicted higher enantioselectivities than those calculated and experimentally tested with C
ALKYLMETAL ASYMMETRIC REDUCTION. XIX. GRIGNARD REAGENTS DERIVED FROM NATURALLY OCCURRING PRODUCTS AS REDUCING AGENTS OF KETONES
Falorni, Massimo,Lardicci, Luciano,Uccello-Barretta, Gloria,Giacomelli, Giampaolo
, p. 495 - 500 (2007/10/02)
Some optically active Grignard reagents from naturally occurring isoprenoid compounds have been prepared and reacted with prochiral ketones.Contrary to what is generally observed with aliphatic alkyl butyl Grignard reagents, no addition took place and onl
