Computer-Assisted Design of Chiral Boron Enolates: The Role of Ate Complexes in Determining Aldol Stereoselectivity.

DOI: 10.1016/S0040-4020(01)80834-6

Source and publish data:

Tetrahedron p. 1227 - 1242 (1994)

Update date:2022-09-26

Topics:

Authors:

Bernardi, Anna

Comotti, Angiolina

Gennari, Cesare

Hewkin, Cheryl T.

Goodman, Jonathan M.

et al. et al.

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Article abstract of DOI:10.1016/S0040-4020(01)80834-6

Transition-state modelling for the aldol reaction of chiral Z and E enol borinates (1 and 2, Scheme 1) bearing mixed ligands (L¹=Ipc, L²=9) predicted higher enantioselectivities than those calculated and experimentally tested with C<

Full text of DOI:10.1016/S0040-4020(01)80834-6

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