31485-87-7

Upstream product

• 20023-67-0 1,2-diphenyl-5,7-di-tert-butylspiro<2.5>octa-1,4,7-trien-6-one 
• 501-65-5 diphenyl acetylene 
• 7078-98-0 2,6-di-tert-butyl-4-benzylidene-cyclohexa-2,5-dienone 
• 1539-57-7 diethyl 2,6-dimethyl-4-benzyl-1,4-dihydropyridine-3,5-dicarboxylate 
• 100-39-0 benzyl bromide 
• 955-02-2 2,6-di-tert-butyl-4-diazo-2,5-cyclohexadien-1-one 

Relevant academic research and scientific papers

Br?nsted acid catalyzed radical addition to quinone methides

A fundamental quest for alkyl radical generation under mild conditions through photoinduced Br?nsted acid catalysis is addressed. The optimized protocol does not require any organic dyes or transition metal photocatalyst. Under blue light irradiation with diphenyl phosphate as a catalyst and dihydropyridine derivatives as a radical source, functionalized arylmethane derivatives are obtained in high yield.

CuH-Catalyzed Asymmetric 1,6-Conjugate Reduction of p-Quinone Methides: Enantioselective Synthesis of Triarylmethanes and 1,1,2-Triarylethanes

The first copper hydride (CuH)-catalyzed asymmetric 1,6-conjugate reduction of p-quinone methides is reported. This protocol provides a new method to access a variety of triarylmethanes and 1,1,2-triarylethanes in good yields with excellent enantioselectivities and broad functional group tolerance.