315-52-6

Upstream product

• 120788-51-4 1,1,4-Trifluoro-1,4-dihydro-naphthalene 
• 91-20-3 naphthalene 
• 1536-66-9 1,4-dichloro-5,8-difluoro-1,2,3,4-tetrahydro-naphthalene 
• 773-70-6 5,8-difluoro-1,2,3,4-tetrahydro-1,4-epoxido-naphthalene 
• 86119-84-8 phosphoric acid 
• 321-38-0 1-Fluoronaphthalene 

Relevant academic research and scientific papers

Fluorination of Bi- and polycyclic aromatic hydrocarbons with N-fluorobis(phenylsulfonyl)amine in the absence of solvent

Reactions of N-fluorobis(phenylsulfonyl)amine with naphthalene, 1-methylnaphthalene, phenanthrene, anthracene, and pyrene without solvent were investigated. Sometimes the fluorination of aromatic compounds with N-fluorobis(phenylsulfonyl)amine without solvent proceeded more selectively than at the use of fluorinating reagents in solution.

Selective and efficient direct fluorination of polycyclic aromatic hydrocarbons using 1-fluoro-4-hydroxy-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate)

A new N-F fluorinating reagent 1-fluoro-4-hydroxy-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate) (Accufluor NFTh) was effectively used for selective fluorination of polycyclic aromatics. Naphthalene was site-selectively fluorinated to 1-fluoronaphthalene, phenanthrene to 9-fluorophenanthrene, and pyrene to 1-fluoropyrene. In a series of substituted naphthalenes the regioselectivity and effectiveness of fluorination depended on the position and the nature of the substituents.