31503-05-6

Upstream product

• 108-86-1 bromobenzene 
• 86544-72-1 2-((trifluoromethylsulfonyl)oxy)-1,7,7-trimethylbicyclo<2.2.1>hept-2-ene 
• 16821-80-0 (1R,2S,4R)-(-)-2-[phenyl]-1,7,7-tri-[methyl]-bicyclo[2.2.1]heptane-2-ol 
• 127-17-3 2-oxo-propionic acid 
• 31503-04-5 Phenylborneol 
• 76-22-2 Camphor 
• 661-69-8 hexamethyldistannane 
• 946498-69-7 (1S,4S)-1,7,7-trimethylbicyclo[2.2.1]hept-2-en-2-yl trifluoromethanesulfonate 
• 28557-00-8 phenylzinc chloride 
• 464-48-2 (1S)-camphor 
• 100-58-3 phenylmagnesium bromide 
• 464-49-3 (1R,4R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one 
• 591-51-5 phenyllithium 
• 736109-58-3 1,7,7-trimethyl-bicyclo[2.2.1]heptan-2-one 

Downstream Products

• 31503-10-3 (1S,2R,3R,4S)-4,7,7-Trimethyl-3-phenyl-bicyclo[2.2.1]heptan-2-ol 
• 959696-54-9 2-exo-Hydroxy-2-endo-phenylbornan-3-on 
• 31503-18-1 2-endo-Hydroxy-2-exo-phenylbornan-3-on 
• 31503-17-0 (-)-(1R,2R,3R,4S)-1,7,7-trimethyl-2-phenyl-bicyclo[2.2.1]heptane-2,3-diol 
• 31503-17-0 2-Endo-3-endo-dihydroxy-2-exo-phenylbornan 
• 30557-98-3 (-)-(1R,2S)-2-endo-phenylbornan-3-one 
• 30557-98-3 (+)-(1R,4S)-exo-2-phenylbornan-3-one 
• 1262791-34-3 [B(C₆F₅)2C₇H₇(CH₃)3(C₆H₅)] 
• 1262791-36-5 [B(C₆F₅)2C₇H₇(CH₃)3(C₆H₅)] 
• 31503-17-0 (1R,2S,3S,4S)-1,7,7-Trimethyl-2-phenyl-bicyclo[2.2.1]heptane-2,3-diol 
• 31503-12-5 2exo-Phenylbornan-3-on 
• 31503-14-7 (1S,2R,3S,4S)-4,7,7-Trimethyl-3-phenyl-bicyclo[2.2.1]heptan-2-ol 
• 31503-13-6 (1S,2S,3R,4S)-4,7,7-Trimethyl-3-phenyl-bicyclo[2.2.1]heptan-2-ol 
• 32663-28-8 2-endo-Phenyl-bornan-3-on 

Relevant academic research and scientific papers

Palladium complex-catalyzed cross-coupling reaction of organobismuth dialkoxides with triflates

(matrix presented) Pd(PPh3)4 catalyzes cross-coupling reaction between organobismuth alkoxides and aryl and vinyl triflates.

Conversion of Carbonyl Compounds to Olefins via Enolate Intermediate

A general and efficient protocol to synthesize substituted olefins from carbonyl compounds via nickel catalyzed C—O activation of enolates was developed. Besides ketones, aldehydes were also suitable substrates for the presented catalytic system to produce di- or tri- substituted olefins. It is worth noting that this approach exhibited good tolerance to highly reactive tertiary alcohols, which could not survive in other reported routes for converting carbonyl compounds to olefins. This method also showed good regio- and stereo-selectivity for olefin products. Preliminary mechanistic studies indicated that the reaction was accomplished through nickel catalyzed C—O activation of enolates, thus offering helpful contribution to current enol chemistry.

Enantioselective hydrogenation with chiral frustrated Lewis Pairs

No subsequent frustration: Frustrated Lewis pairs (FLPs) have been recently introduced as an unprecedented possibility to activate hydrogen. On the basis of this concept the first example of highly enantioselective catalytic hydrogenation of imines using

Renewable camphor-derived hydroperoxide: Synthesis and use in the asymmetric epoxidation of allylic alcohols

Renewable enantiopure tertiary furyl hydroperoxide has been easily synthesized in two steps starting from low cost (+)-(1R)-camphor and it has been used in the asymmetric epoxidation and kinetic resolution of allylic alcohols (enantioselectivities up to 46%).

THE OCTANT RULE XXIII. ANTIOCTANT EFFECTS IN γ,δ-UNSATURATED KETONES

The exo and endo α-benzyl derivatives (1 and 2. respectively) of (+)-camphor have been synthesized and are found to exert a strong influence on the circular dichroism n?* Cotton effects: 1: Δε301max -0.36 (n-heptane) and 2: Δε302max +3.22, relative to camphor: Δε304max + 1.8 (n-heptane).Evidence for electric dipole transition moment coupling in these γ,δ-unsaturated systems is found in the n?* UV: 1: ε291max 84 (n-heptane) and 2: ε285max 303, relative to camphor: ε290max 25.