959696-54-9Relevant articles and documents
Stereoselektive Synthese von Alkoholen, VI. Asymmetrische Synthesen von 4-Penten-2-ol ueber Allylboronsaeureester chiraler Glycole
Herold, Thomas,Schrott, Ursula,Hoffmann, Reinhard W.
, p. 359 - 374 (2007/10/02)
Allylboronates 3 of substituted camphor glycols 2 add to acetaldehyde giving 4-penten-2-ol (1).The substituents affect the extent of asymmetric induction in an additive manner.Pentenol of 86percent enantiomeric purity was obtained using 2d as chiral matrix.