315180-72-4

Upstream product

• 3282-30-2 pivaloyl chloride 
• 315180-68-8 (2S,3S,4R)-1-benzyloxy-2,4-bis(2,2-dimethylpropanoyloxymethyl)-3-hydroxy-5-(4-methoxybenzoyloxy)pentane 
• 315180-76-8 (2S,3S,4R)-2,4-bis(2,2-dimethylpropanoyloxymethyl)-5-(4-methoxybenzoyloxy)pentane-1,3-diol 
• 315180-71-3 (2S,3S,4R)-2,4-bis(2,2-dimethylpropanoyloxymethyl)-3,5-[(S)-4-methoxybenzylidenedioxy]pentan-1-ol 
• 315180-67-7 (2S,3R,4R)-2,4-bis(2,2-dimethylpropanoyloxymethyl)-3,5-[(S)-4-methoxybenzylidenedioxy]pentanal 
• 302783-25-1 3-C-benzyloxymethyl-3-deoxy-1,2-O-isopropylidene-5,6-O-(4-methoxybenzylidene)-α-D-allofuranose 
• 98039-29-3 3-C-benzyloxymethyl-3-deoxy-1,2-O-isopropylidene-6-O-(4-methoxybenzyl)-α-D-ribo-hexofuranos-5-ulose 
• 98039-21-5 3-C-benzyloxymethyl-3,5,6-trideoxy-1,2-O-isopropylidene-5-C-(4-methoxybenzyloxymethyl)-α-D-ribo-hex-5-enofuranose 
• 98039-20-4 3-C-benzyloxymethyl-3-deoxy-1,2-O-isopropylidene-6-O-(4-methoxybenzylidene)-α-D-allofuranose 
• 85315-68-0 3-C-(benzyloxymethyl)-3-deoxy-1,2-O-isopropylidene-α-D-allofuranose 

Relevant academic research and scientific papers

Studies on the synthesis of myriaporones: Stereoselective synthesis of the C5-C13 fragment starting from D-glucose via regioselective reductive opening of methoxybenzylidene acetal

A stereoselective synthesis is described of the C5-C13 fragment (4) of myriaporone 4 (1) starting from D-glucose by a coupling of the C5-C9 aldehyde (5), prepared using a regioselective reductive ring-opening of methoxybenzylidene acetal, with the C10-C13 iodoolefin (6).