98039-20-4

Basic information

• Product Name: 3-C-benzyloxymethyl-3-deoxy-1,2-O-isopropylidene-6-O-(4-methoxybenzylidene)-α-D-allofuranose
• Synonyms: 3-C-benzyloxymethyl-3-deoxy-1,2-O-isopropylidene-6-O-(4-methoxybenzylidene)-α-D-allofuranose
• CAS NO: 98039-20-4
• Molecular Weight: 444.525
• Mol File: 98039-20-4.mol

Chemical Properties

• CAS DataBase Reference: 3-C-benzyloxymethyl-3-deoxy-1,2-O-isopropylidene-6-O-(4-methoxybenzylidene)-α-D-allofuranose(CAS DataBase Reference)
• NIST Chemistry Reference: 3-C-benzyloxymethyl-3-deoxy-1,2-O-isopropylidene-6-O-(4-methoxybenzylidene)-α-D-allofuranose(98039-20-4)
• EPA Substance Registry System: 3-C-benzyloxymethyl-3-deoxy-1,2-O-isopropylidene-6-O-(4-methoxybenzylidene)-α-D-allofuranose(98039-20-4)

Safety Data

• Hazardous Substances Data: 98039-20-4(Hazardous Substances Data)

Upstream product

• 85315-69-1 3-C-(benzyloxymethyl)-3-deoxy-1,2-O-isopropylidene-6-O-tosyl-α-D-allofuranose 
• 85315-67-9 3-C-(benzyloxymethyl)-3-deoxy-1,2:5,6-di-O-isopropylidene-α-D-allofuranose 
• 100-44-7 benzyl chloride 
• 69832-48-0 ((3aR,5S,6R,6aR)-tetrahydro-2,2-dimethyl-5-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)furo[2,3-d][1,3]dioxol-6-yl)methanol 
• 85315-68-0 3-C-(benzyloxymethyl)-3-deoxy-1,2-O-isopropylidene-α-D-allofuranose 
• 2186-92-7 p-Anisaldehyde dimethyl acetal 
• 824-94-2 p-methoxybenzyl chloride 
• 53942-86-2 4-methoxybenzyl alcohol sodium salt 
• 86654-59-3 5,6-anhydro-3-C-benzyloxymethyl-3-deoxy-1,2-O-isopropylidene-α-D-allofuranose 

Downstream Products

• 98039-23-7 3-C-benzyloxymethyl-3,5-dideoxy-1,2-O-isopropylidene-6-O-(4-methoxybenzyl)-5-C-methyl-α-D-allofuranose 
• 98039-22-6 3-C-benzyloxymethyl-3,5-dideoxy-1,2-O-isopropylidene-6-O-(4-methoxybenzyl)-5-C-methyl-β-L-talofuranose 
• 315180-72-4 2,2-Dimethyl-propionic acid (E)-(2R,6R)-7-(tert-butyl-diphenyl-silanyloxy)-2-[(2S,4R,5R)-5-(2,2-dimethyl-propionyloxymethyl)-2-(4-methoxy-phenyl)-[1,3]dioxan-4-yl]-3-hydroxy-4,6-dimethyl-hept-4-enyl ester 
• 315180-68-8 (2S,3S,4R)-1-benzyloxy-2,4-bis(2,2-dimethylpropanoyloxymethyl)-3-hydroxy-5-(4-methoxybenzoyloxy)pentane 
• 315180-77-9 2,2-Dimethyl-propionic acid (4S,5R)-4-[(S)-1-benzyloxymethyl-2-(2,2-dimethyl-propionyloxy)-ethyl]-2-(4-methoxy-phenyl)-[1,3]dioxan-5-ylmethyl ester 
• 315180-76-8 (2S,3S,4R)-2,4-bis(2,2-dimethylpropanoyloxymethyl)-5-(4-methoxybenzoyloxy)pentane-1,3-diol 
• 315180-71-3 (2S,3S,4R)-2,4-bis(2,2-dimethylpropanoyloxymethyl)-3,5-[(S)-4-methoxybenzylidenedioxy]pentan-1-ol 
• 315180-67-7 (2S,3R,4R)-2,4-bis(2,2-dimethylpropanoyloxymethyl)-3,5-[(S)-4-methoxybenzylidenedioxy]pentanal 
• 98039-21-5 3-C-benzyloxymethyl-3,5,6-trideoxy-1,2-O-isopropylidene-5-C-(4-methoxybenzyloxymethyl)-α-D-ribo-hex-5-enofuranose 
• 98039-29-3 3-C-benzyloxymethyl-3-deoxy-1,2-O-isopropylidene-6-O-(4-methoxybenzyl)-α-D-ribo-hexofuranos-5-ulose 

Relevant articles and documents

Studies on the synthesis of myriaporones: Stereoselective synthesis of the C5-C13 fragment starting from D-glucose via regioselective reductive opening of methoxybenzylidene acetal

A stereoselective synthesis is described of the C5-C13 fragment (4) of myriaporone 4 (1) starting from D-glucose by a coupling of the C5-C9 aldehyde (5), prepared using a regioselective reductive ring-opening of methoxybenzylidene acetal, with the C10-C13 iodoolefin (6).

Chiral Synthesis of Polyketide-derived Natural Products. Part 5. Synthesis of a Chiral Segment Corresponding to the C-1-C-5 Unit of Erythromycin A from D-Glucose

As a right-hand segment with three consecutive chiral centres corresponding to the C-1-C-5 unit of erythromycin A (1), (2S,3R,4S)-3,5-isopropylidenedioxy-2,4-dimethylpentanal (32) was synthesized from D-glucose (5) by application of MPM (4-methoxybenzyl)