315668-01-0

Basic information

• Product Name: 4-hydroxyphenyl N,N-diisopropylcarbamate
• Synonyms: 4-hydroxyphenyl N,N-diisopropylcarbamate
• CAS NO: 315668-01-0
• Molecular Weight: 237.299
• Mol File: 315668-01-0.mol

Chemical Properties

• CAS DataBase Reference: 4-hydroxyphenyl N,N-diisopropylcarbamate(CAS DataBase Reference)
• NIST Chemistry Reference: 4-hydroxyphenyl N,N-diisopropylcarbamate(315668-01-0)
• EPA Substance Registry System: 4-hydroxyphenyl N,N-diisopropylcarbamate(315668-01-0)

Safety Data

• Hazardous Substances Data: 315668-01-0(Hazardous Substances Data)

Upstream product

• 19009-39-3 N,N-diisopropylcarbamoyl chloride 
• 123-31-9 hydroquinone 

Downstream Products

• 315668-02-1 4-(methoxymethoxy)phenyl N,N-diisopropylcarbamate 
• 315668-40-7 N,N,N',N'-tetraisopropyl 3,6-bis(trimethylsilyl)benzene-1,4-diyl dicarbamate 
• 315668-33-8 2-(diisopropylcarbamoyl)-4-(methoxymethoxy)-6-(trimethylsilyl)phenyl propionate 
• 315668-34-9 2-(diisopropylcarbamoyl)-4-hydroxy-6-(trimethylsilyl)phenyl propionate 
• 315668-28-1 N,N-diisopropyl-2-hydroxy-5-(methoxymethoxy)-3-(trimethylsilyl)benzamide 
• 315668-13-4 2-(diisopropylcarbamoyl)-4-(methoxymethoxy)phenyl propionate 
• 315668-25-8 4-(methoxymethoxy)-2-(trimethylsilyl)phenyl N,N-diisopropyl carbamate 
• 315668-11-2 2-[(diisopropylamino)carbonyl]-4-hydroxyphenyl propionate 
• 315668-06-5 N,N-diisopropyl-2-hydroxy-5-(methoxymethoxy)benzamide 
• 210104-13-5 2-(diisopropylcarbamoyl)benzene-1,4-diol 
• 315668-39-4 N,N,N',N'-tetraisopropyl benzene-1,4-diyl dicarbamate 

Relevant articles and documents

Atropisomeric benzamides and naphthamides as chiral auxiliaries

Atropisomeric compounds whose chirality resides in a rotationally restricted aryl-CONR2 bond may be employed as chiral auxiliaries. The electron-withdrawing amide group causes problems in the diastereoselective functionalisation of enolates derived from atropisomeric phenyl esters, but a strategy based on atroposelective nucleophilic addition to a chiral aldehyde followed by stereospecific [3,3] sigmatropic rearrangement allows atropisomeric naphthamides to be used as auxiliaries. The auxiliaries are resolved by dynamic resolution during aminal formation using a proline-derived diamine. The Royal Society of Chemistry 2000.