31599-49-2Relevant academic research and scientific papers
Ceric ammonium nitrate as the novel oxidizing agent for the facile synthesis of (dichloroiodo)arenes
Tale, Nilesh P.,Shelke, Amol V.,Karade, Nandkishor N.
experimental part, p. 2959 - 2965 (2012/07/27)
Ceric ammonium nitrate (CAN) has been found to be a remarkable oxidizing agent for the oxidative conversion of iodoarenes to (dichloroiodo)arenes in acetic acid using aqueous HCl. The reaction of CAN with HCl generates in situ molecular chlorine, which is responsible for the oxidation. This method avoids the use of hazardous, toxic, and corrosive gaseous chlorine.
A solvent-free synthesis of (dichloroiodo)arenes from iodoarenes
Zielinska, Agnieszka,Skulski, Lech
, p. 1087 - 1089 (2007/10/03)
An efficient solid-state oxidation of iodoarenes, ArI, is described using the urea-hydrogen peroxide adduct (UHP), a stable, inexpensive, and easily handled oxidant. The reactions were complete in 15min at 85°C. The melts thus obtained were reacted with e
