316129-28-9Relevant academic research and scientific papers
Nucleophilic ring opening of mono-activated cyclopropanes with arylselenolates generated from diselenides in the presence of a Zn/AlCl 3 system
Nazari, Mohammad,Movassagh, Barahman
experimental part, p. 1803 - 1805 (2009/12/04)
An efficient one-pot synthesis of γ-arylselenenyl ketones, acids, and nitriles is presented. The method uses Zn/AlCl3-promoted cleavage of diselenides and subsequent ring-opening of mono-activated cyclopropanes. Georg Thieme Verlag Stuttgart.
Nucleophilic cleavage of lactones and esters with zinc selenolates prepared from diselenides in the presence of Zn/AlCl3
Nazari, Mohammad,Movassagh, Barahman
scheme or table, p. 438 - 441 (2009/05/27)
The utility of zinc selenolates for effecting nucleophilic cleavage of simple lactones and esters has been investigated. When zinc selenolate generated via Zn/AlCl3-promoted cleavage of diselenides was reacted with simple lactones and esters, efficient nucleophilic alkyl-oxygen bond cleavage proceeded generating the corresponding carboxylic acids in moderate to excellent yields.
New syntheses of the C,D-ring pyrromethenones of phytochrome and phycocyanin
Jacobi,DeSimone,Ghosh,Guo,Leung,Pippin
, p. 8478 - 8489 (2007/10/03)
Pyrromethenone 7, the C,D-ring segment of phytochrome (Pr, 4), has been prepared in an efficient fashion employing three new strategies. Each of these has potential advantages for the synthesis of labeled material. Our first approach is related to the Gos
