316377-63-6

Basic information

• Product Name: Cyclopropane, 1-chloro-2-[(3E)-4-chloro-3-buten-1-ynyl]-, (1R,2S)- (9CI)
• Synonyms: Cyclopropane, 1-chloro-2-[(3E)-4-chloro-3-buten-1-ynyl]-, (1R,2S)- (9CI)
• CAS NO: 316377-63-6
• Molecular Formula: C7H6Cl2
• Molecular Weight: 161.02854
• Product Categories: HALIDE
• Mol File: 316377-63-6.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Cyclopropane, 1-chloro-2-[(3E)-4-chloro-3-buten-1-ynyl]-, (1R,2S)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclopropane, 1-chloro-2-[(3E)-4-chloro-3-buten-1-ynyl]-, (1R,2S)- (9CI)(316377-63-6)
• EPA Substance Registry System: Cyclopropane, 1-chloro-2-[(3E)-4-chloro-3-buten-1-ynyl]-, (1R,2S)- (9CI)(316377-63-6)

Safety Data

• Hazardous Substances Data: 316377-63-6(Hazardous Substances Data)

Upstream product

• 156-60-5 trans-1,2-dichloroethylene 
• 316377-61-4 trans-2-chlorocyclopropylacetylene 
• 316377-60-3 trans-2-chloro-1-(2,2'-dibromoethynyl)-cyclopropane 

Relevant articles and documents

Synthetic studies on the trans-chlorocyclopropane dienyne side chain of callipeltoside A.

[structure] Enantiomerically enriched trans-chlorocyclopropanemethanol was obtained by lipase kinetic resolution of dichlorocyclopropanemethanol 3, followed by reduction. The sp-sp(2) bond of the trans-chlorocyclopropane dienyne side chain of callipeltoside A was constructed via a Stille coupling reaction of 1, 1-dibromo-1-alkene 7 and a vinylstannane in a highly dipolar solvent capable of promoting HBr elimination to give internal alkynes.