31656-49-2Relevant articles and documents
Intermolecular coupling and intramolecular cyclization of aryl nitriles on Au(111)
Klaasen, Henning,Liu, Lacheng,Gao, Hong-Ying,Viergutz, Lena,Held, Philipp A.,Knecht, Tobias,Meng, Xiangzhi,B?rner, Melanie C.,Barton, Dennis,Amirjalayer, Saeed,Neugebauer, Johannes,Studer, Armido,Fuchs, Harald
supporting information, p. 11611 - 11614 (2019/10/02)
The on-surface dimerization reaction of an organic nitrile on Au(111) is reported. The formation of the product, which contains five newly formed σ-bonds and a diazapyrene core structure, was investigated and characterized by scanning tunneling microscopy. Experimental and computational studies of reference compounds support our findings.
Corresponding amine nitrile and method of manufacturing thereof
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Paragraph 0132; 0133; 0134; 0136, (2018/05/24)
The invention relates to a preparation method of nitrile. Compared with the prior art, the preparation method has the characteristics of obvious reduction of the usage amount of ammonia sources, low environmental pressure, low energy consumption, low production cost, high purity and yields of nitrile products, and the like, and can be used for obtaining nitrile with a more complex structure. The invention also relates to a method for preparing corresponding amine with nitrile.
Dicyanoaromatic radical anions as mixed valence species
Moneo, Alvaro,Carvalho, M. Fernanda N. N.,Telo, Joao P.
experimental part, p. 559 - 565 (2012/08/28)
The reduction of nine symmetric dicyanoaromatic radical anions by sodium amalgam in the presence of cryptand[2.2.2] was studied using cyclic voltammetry and using optical and electron paramagnetic resonance (EPR) spectroscopies in two aprotic solvents. Al
