31720-69-1

Upstream product

• 60-29-7 diethyl ether 
• 26775-54-2 2-dichloromethyl-2-methyl-cyclohexanone 
• 14789-75-4 6-dichloromethyl-6-methylcyclohexa-2,4-dien-1-one 
• 1193-46-0 2,2-dimethylcyclohexanol 
• 75295-90-8 1-tert-Butyl-1-chloro-cyclopentane 
• 1193-47-1 2,2-dimethyl-cyclohexanone 
• 75-16-1 methylmagnesium bromide 
• 676-58-4 methylmagnesium chloride 
• 917-64-6 methyl magnesium iodide 

Downstream Products

• 69745-49-9 1,6,6-trimethylcyclohexene 
• 91016-16-9 N-<1,2,2-Trimethyl-cyclohexyl>-formamid 
• 87887-12-5 (+)-(1'R,2S,6'S)-1-(2',2',6'-trimethyl-1'-cyclohexyloxy)-2-pentanol 
• 102653-39-4 1,2,2-Trimethyl-cyclohexylamin 
• 7094-26-0 1,1,2-trimethylcyclohexane 
• 103906-16-7 1-Methylamino-1,2,2-trimethyl-cyclohexan 
• 4351-01-3 1,2,2-trimethyl-cyclohexanecarboxylic acid 

Relevant academic research and scientific papers

Some studies on the solvolysis of 1-chloro-1-alkyl cycloalkanes

The effect of the bulk of the sidechain on the rate of solvolysis of 1-alkyl cyclopentyl, cyclohexyl, and cycloheptyl chlorides has been studied.With the exception of the t-butyl systems, the ratio of solvolysis rates for the three ring systems falls in a given series.The slower rate of solvolysis in the six-membered ring system may be due to an extra activation energy contribution caused by the conversion of a neutral chair form to the twist boat or half chair conformation, prior to the actual solvolysis.In the case of five- and seven-membered ring systems the formation of an intermediate carbonium ion is sterically favoured (I-strain or eclipsing interaction) consistent with earlier findings.The faster rate of solvolysis of 1-t-butylcycloalkyl chlorides is likely due to a rearrangement reaction where alkyl participation enhances the rate of solvolysis.