31729-66-5

Basic information

• Product Name: 1-phenylcyclopropanemethanol
• Synonyms: 1-phenylcyclopropanemethanol;1-Phenyl-1-(hydroxymethyl)cyclopropane
• CAS NO: 31729-66-5
• Molecular Formula: C₁₀H₁₂O
• Molecular Weight: 148.20168
• EINECS: 250-781-9
• Mol File: 31729-66-5.mol
• Article Data: 11

Chemical Properties

• Boiling Point: 248.957 °C at 760 mmHg
• Flash Point: 113.108 °C
• Appearance: /
• Density: 1.102 g/cm³
• Vapor Pressure: 0.012mmHg at 25°C
• Refractive Index: 1.575
• Storage Temp.: Sealed in dry,Room Temperature
• PKA: 15.10±0.10(Predicted)
• CAS DataBase Reference: 1-phenylcyclopropanemethanol(CAS DataBase Reference)
• NIST Chemistry Reference: 1-phenylcyclopropanemethanol(31729-66-5)
• EPA Substance Registry System: 1-phenylcyclopropanemethanol(31729-66-5)

Safety Data

• Hazardous Substances Data: 31729-66-5(Hazardous Substances Data)

Usage

General Description

1-Phenylcyclopropanemethanol is a chemical compound that consists of a cyclopropane ring with a phenyl group and a hydroxyl group attached. It is a chiral compound, meaning it has a non-superimposable mirror image, and can exist in two different enantiomeric forms. This chemical has been studied for its potential use in the synthesis of pharmaceuticals and other organic compounds. It may also have applications in organic chemistry research and as a building block in the creation of new molecules with specific properties. Additionally, 1-phenylcyclopropanemethanol could have potential uses in the development of new materials or as a precursor for the synthesis of other complex organic molecules. Overall, this compound has garnered attention for its potential applications in various fields of chemistry and pharmaceutical research.

InChI:InChI=1/C10H12O/c11-8-10(6-7-10)9-4-2-1-3-5-9/h1-5,11H,6-8H2

Upstream product

• 6120-95-2 1-phenyl-1-cyclopropane carboxylic acid 
• 140-29-4 phenylacetonitrile 
• 6121-42-2 1-Phenyl-cyclopropanecarboxylic acid methyl ester 
• 935-44-4 1-cyano-1-phenylcyclopropane 
• 103-79-7 1-phenyl-acetone 
• 1007-71-2 1-(1-phenyl-cyclopropyl)-ethanone 
• 75-11-6 diiodomethane 
• 582-24-1 1-phenyl-2-hydroxyethanone 
• 63201-02-5 1-phenylcyclopropanecarbonyl chloride 
• 87328-17-4 ethyl 1-phenyl-1-cyclopropanecarboxylate 
• 570431-52-6 1-phenylcycloprop-2-ene carboxylic acid methyl ester 
• 682760-41-4 (1-phenylcycloprop-2-en-1-yl)methanol 

Downstream Products

• 91132-82-0 carbamic acid-(1-phenyl-cyclopropylmethyl ester) 
• 1384156-00-6 (R)-3-methylene-5-(1-phenylcyclopropyl)dihydrofuran-2(3H)-one 

Relevant articles and documents

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Electrophilic Bromolactonization of Cyclopropyl Diesters Using Lewis Basic Chalcogenide Catalysts

An efficient and regioselective electrophilic bromolactonization of cyclopropylmethyl diesters using triphenylphosphine sulfide (Ph3PS) or diphenyl selenide (Ph2Se) as the Lewis basic chalcogenide catalyst has been developed. It was observed that Ph3PS favored the formation of anti-diastereomer and yielded the multi-functional γ-lactones. Interestingly, the diastereoselectivity was reversed when using Ph2Se as a catalyst where the syn-product instead of the anti-product was favored. (Figure presented.).

Ruthenium-Catalyzed Deaminative Hydrogenation of Aliphatic and Aromatic Nitriles to Primary Alcohols

The deaminative hydrogenation of nitriles towards alcohols is a useful reaction to transform nitriles into alcohols with NH3 as the sole byproduct. Using the simple and robust RuHCl(CO)(PPh3)3 complex as a catalyst, at low H2 pressures a series of aliphatic and aromatic nitriles could be transformed into the corresponding alcohols. Suitable solvent systems for these reactions were 1,4-dioxane/water and EtOH/water mixtures. In most cases, the selectivity for the alcohols was excellent, and the corresponding amines were formed only in trace amounts.