317339-72-3

Upstream product

• 64741-13-5 3-thiophenyl-3-sulfolene 
• 317339-60-9 4-phenylsulfanyl-1-(toluene-4-sulfonyl)-5,6-dihydro-1H-pyridin-2-one 
• 1011302-75-2 3,6-dihydro-4-phenylsulfonyl-1-tosylpyridin-2(1H)-one 
• 4083-64-1 Tosyl isocyanate 

Downstream Products

• 317339-82-5 dimethyl 2-{1-[(4-methylphenyl)sulfonyl]-6-oxo-1,2,3,6-tetrahydro-4-pyridinyl}malonate 
• 411240-90-9 4-benzyl-1-(toluene-4-sulfonyl)-5,6-dihydro-1H-pyridin-2-one 
• 1011302-78-5 3,4-dihydro-6-hydroxy-2-tosylisoquinolin-1(2H)-one 
• 1011302-75-2 3,6-dihydro-4-phenylsulfonyl-1-tosylpyridin-2(1H)-one 
• 411240-91-0 ethyl 2-{1-[(4-methylphenyl)sulfonyl]-6-oxo-1,2,3,6-tetrahydro-4-pyridinyl}acetate 
• 317339-77-8 4-methyl-1-tosyl-5,6-dihydropyridin-2(1H)-one 
• 29637-85-2 1-tosyl-pyridin-2(1H)-one 

Relevant academic research and scientific papers

Cycloaddition reactions of 4-sulfur-substituted dihydro-2-pyridones and 2-pyridones with conjugated dienes

Cycloaddition reactions of sulfoxide- and sulfone-substituted dihydro-2-pyridones and 2-pyridones with electron-rich dienes gave new bicyclic and tricyclic products in good to fair yields. The reactivity, regioselectivity, and stereoselectivity of these r

Synthesis and applications of tetrahydro-2-pyridinones via aza-Diels - Alder reactions of thio-substituted 1,3-dienes with arylsulfonyl isocyanates

The first aza-Diels - Alder reactions of arylsulfonyl isocyanates with thio-substituted 1,3-dienes via the 3-sulfolene precursors 1 gave the cyclized products 3 with complete control of chemo- and regioselectivity. The cyclized products 3a and 5 underwent further reactions with nucleophiles and bases to give useful heterocyclic compounds. The N-tosyl group of the cyclic products could be selectively replaced by hydrogen or another substituent.

Aza-Diels-Alder reactions and synthetic applications of thio-substituted 1,3-dienes with arylsulfonyl isocyanates

The first aza-Diels-Alder reactions of arylsulfonyl isocyanates with thio-substituted 1,3-dienes via the 3-sulfolene precursors 1 gave the cyclized products 3 with complete control of regio- and chemoselectivity. The cyclized products 3a and 4 underwent further interesting reactions with nucleophiles and bases to give useful heterocyclic compounds. (C) 2000 Elsevier Science Ltd.