31736-34-2 Usage
General Description
Cinnamyl methacrylate is a chemical compound with the formula C11H12O2. It is a clear, colorless liquid with a characteristic sweet, balsamic odor. Cinnamyl methacrylate is used as a monomer in the production of various polymers and copolymers, particularly in the synthesis of resins, adhesives, and coatings. It is also used in the production of fragrances and flavors, as it imparts a sweet, oriental note reminiscent of cinnamon. Cinnamyl methacrylate is considered to be a skin and eye irritant, and exposure to high concentrations may cause respiratory irritation and allergic reactions in some individuals. It is important to handle this chemical with care and in accordance with safety guidelines to minimize potential health risks.
Check Digit Verification of cas no
The CAS Registry Mumber 31736-34-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,1,7,3 and 6 respectively; the second part has 2 digits, 3 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 31736-34:
(7*3)+(6*1)+(5*7)+(4*3)+(3*6)+(2*3)+(1*4)=102
102 % 10 = 2
So 31736-34-2 is a valid CAS Registry Number.
InChI:InChI=1/C13H14O2/c1-11(2)13(14)15-10-6-9-12-7-4-3-5-8-12/h3-9H,1,10H2,2H3/b9-6+
31736-34-2Relevant articles and documents
A 1,3,2-Diazaphospholene-Catalyzed Reductive Claisen Rearrangement
Reed, John H.,Donets, Pavel A.,Miaskiewicz, Solène,Cramer, Nicolai
supporting information, p. 8893 - 8897 (2019/05/28)
1,3,2-Diazaphospholenes (DAPs) are an emerging class of organic hydrides. In this work, we exploited them as efficient catalysts for very mild reductive Claisen rearrangements. The method is tolerant towards a wide variety of functional groups and operates at ambient temperature. Besides being enantiospecific for substrates with existing stereogenic centers, the diastereoselectivity can be switched by varying solvents and DAP catalysts. The reaction kinetics show direct rearrangements of O-bound phospholene enolates and provide a proof-of-principle for catalytic enantioselective reactions.
