31787-33-4

Upstream product

• 13063-57-5 isobutyraldehyde dimethylhydrazone 
• 614-47-1 1,3-diphenyl-propen-3-one 
• 4111-54-0 lithium diisopropyl amide 
• 78414-83-2 4-benzoyl-2,2-dimethyl-3-phenylbutyronitrile O-carboxymethyloxime 
• 78-82-0 Isobutyronitrile 
• 94-41-7 benzalacetophenone 
• 41658-69-9 2-bromo-2-methyl-propionitrile 

Downstream Products

• 78414-89-8 4-cyano-4-methyl-3-phenylvalerophenone azine 
• 78414-83-2 4-benzoyl-2,2-dimethyl-3-phenylbutyronitrile O-carboxymethyloxime 

Relevant academic research and scientific papers

Iminyls. Part 8. Intramolecular Addition to Nitrile Group

Evidence for the radical polymerisation of nitrile groups in polyacrylonitrile has been sought using model compounds.No evidence for the cycloaddition of iminyls to nitrile groups has been obtained but nucleophilic addition occured easily.Thus, 1,8-dicyan

ADDITIONS REGIOSELECTIVES D'IMINES ET D'HYDRAZONES METALLEES AUX α-ENONES

The behavior of metallated imines and hydrazones toward α,β-unsaturated ketones was studied, using different reaction times and temperatures.Dissociation of the functional group (imine or hydrazone) in the adducts and regioselectivity in their condensation reactions are discussed.The first example of reversible addition to the carbonyl group of an enone is demonstrated for the reaction between trans chalcone and (1-)*Li(1+).