318472-84-3

Upstream product

• 37605-46-2 (propa-1,2-diene-1-sulfinyl)benzene 
• 100-53-8 phenylmethanethiol 
• 931-59-9 benzenesulfenyl chloride 

Downstream Products

• 150-60-7 dibenzyl disulphide 
• 87295-68-9 Z-3-(benzenesulfinyl)-2-ethylprop-2-en-1-ol 
• 87309-96-4 Z-3-benzenesulfinyl-2-phenylprop-2-en-1-ol 

Relevant academic research and scientific papers

Convenient stereoselective synthesis of 3-hydroxy-2-iodo-2(E)-alkenyl sulfides via iodohydroxylation of 1,2-allenyl sulfoxides in the presence of BnSH

The iodohydroxylation of 1,2-allenyl sulfoxides with I2 in the presence of BnSH affords 3-hydroxy-2-iodo-2(E)-alkenyl sulfides in good yields and selectivities. The stereochemistry for the products of this transformation is opposite to what was obtained from the iodohydroxylation of 1,2-allenyl sulfides. Based on the results of some control experiment, a mechanism was proposed.

Highly regio- and stereoselective halohydroxylation reaction of 1,2-allenyl phenyl sulfoxides. Reaction scope, mechanism, and the corresponding Pd- or Ni-catalyzed selective coupling reactions

A highly regio- and stereoselective halohydroxylation of 1,2-allenyl sulfoxides with X+ and water was developed. The reaction shows E-stereoselectivity. In the iodohydroxylation reaction, I2 was used to introduce the iodine atom. For

Unique Selectivity of Iodohydroxylation Reaction of Allenyl Phenyl Sulfoxides in Aqueous MeCN. A Stereodefined Synthesis of (E)-2-iodo-3-hydroxy-1-alkenyl Sulfoxides

equation presented Iodohydroxylation reaction of allenyl phenyl sulfoxides with I2 can smoothly proceed to generate (E)-2-iodo-3-hydroxy-1-alkenyl sulfoxides with excellent regio- and stereoselectivity in high or excellent yields. The configura