87295-68-9Relevant academic research and scientific papers
Highly regio- and stereoselective halohydroxylation reaction of 1,2-allenyl phenyl sulfoxides. Reaction scope, mechanism, and the corresponding Pd- or Ni-catalyzed selective coupling reactions
Ma, Shengming,Ren, Hongjun,Wei, Qi
, p. 4817 - 4830 (2007/10/03)
A highly regio- and stereoselective halohydroxylation of 1,2-allenyl sulfoxides with X+ and water was developed. The reaction shows E-stereoselectivity. In the iodohydroxylation reaction, I2 was used to introduce the iodine atom. For
Applications des reactifs de Grignard vinyliques γ-functionnels a la synthese de nouveaux composes soufres
Doboudin, Jean-Georges,Jousseaume, Bernard,Thoumazeau, Elisabeth
, p. 105 - 108 (2007/10/02)
In previous publications we had examined synthetic methods involving new γ-functional vinylic Grignard reagents 1 and their reactivities toward halogenated and carbonyl derivatives.Since numerous synthetic applications of α,β- and β,γ-unsaturated sulfur c
