3185-66-8

Basic information

• Product Name: Phosphoric triamide, N,N,N',N'-tetraethyl-N''-phenyl-
• CAS NO: 3185-66-8
• Molecular Formula: C14H26N3OP
• Molecular Weight: 283.354
• Mol File: 3185-66-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Phosphoric triamide, N,N,N',N'-tetraethyl-N''-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphoric triamide, N,N,N',N'-tetraethyl-N''-phenyl-(3185-66-8)
• EPA Substance Registry System: Phosphoric triamide, N,N,N',N'-tetraethyl-N''-phenyl-(3185-66-8)

Safety Data

• Hazardous Substances Data: 3185-66-8(Hazardous Substances Data)

Usage

General Description

Phosphoric triamide, N,N,N',N'-tetraethyl-N''-phenyl- is a chemical compound with the molecular formula C14H30N3O3P. It is a derivative of phosphoric triamide, with four ethyl groups and one phenyl group attached to the nitrogen atoms. Phosphoric triamide, N,N,N',N'-tetraethyl-N''-phenyl- is primarily used as a reagent in organic synthesis, particularly in the formation of amides and other nitrogen-containing compounds. It can also be used as a catalyst in certain reactions, and as a stabilizer in certain industrial processes. It is important to handle this chemical with care, as it may have hazardous properties and should be used in a well-ventilated area with appropriate protective equipment.

Upstream product

• 109-89-7 diethylamine 
• 62-53-3 aniline 
• 622-37-7 Phenyl azide 
• 3185-83-9 tetraethyl-N''-phenylphosphorodiamidimidic chloride 
• 685-83-6 bis(diethylamino)chlorophosphine 
• 1794-24-7 tetraethyldiamidochlorophosphate 

Relevant articles and documents

Versatile PNPO ligands for palladium and nickel catalyzed ethylene polymerization and copolymerization with polar monomers

Asymmetric PO-type ligands are versatile platforms for palladium and nickel catalyzed ethylene polymerization as well as copolymerization of ethylene with polar monomers. In this work, a series of phosphinoamine phosphoramidate/phosphoramide ligands and the corresponding palladium/nickel catalysts were prepared, characterized and investigated in ethylene polymerization as well as copolymerization of ethylene with various polar monomers. The palladium and nickel complexes exhibited high activities in ethylene (co) polymerization, generating high-molecular-weight polyethylenes and copolymers of ethylene and polar monomers. The introduction of electron-donating substituents in the palladium catalytic system can significantly increase polymer molecular weights while maintaining high ethylene (co)polymerization activities. The less electronic donating substituents in the nickel catalysts led to increased catalytic activities in both ethylene polymerization and copolymerization with polar monomers. These results demonstrate the importance of ligand electronic effect in tuning the properties of nickel and palladium catalysts in ethylene polymerization and copolymerization reactions.

Covalent Alternatives for the Elusive Iminophosphonium Cation. Crystal Structure of PCl(NPri2)2NPh*AlCl3 and P(NPri2)2O

Reactions between diaminoiminophosphinic chlorides and the chloride-abstracting agents AlCl3 and Ag(SO3CF3) have been comprehensively examined as potential routes to the three-co-ordinate iminophosphonium cation.However, bis(dialkylimino)(phenylimino)phos