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31904-29-7

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31904-29-7 Usage

Chemical Properties

dark orange liquid

Check Digit Verification of cas no

The CAS Registry Mumber 31904-29-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,1,9,0 and 4 respectively; the second part has 2 digits, 2 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 31904-29:
(7*3)+(6*1)+(5*9)+(4*0)+(3*4)+(2*2)+(1*9)=97
97 % 10 = 7
So 31904-29-7 is a valid CAS Registry Number.
InChI:InChI=1/C9H13.C5H5.Fe/c1-2-3-6-9-7-4-5-8-9;1-2-4-5-3-1;/h4-5,7-8H,2-3,6H2,1H3;1-5H;

31904-29-7 Well-known Company Product Price

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  • Alfa Aesar

  • (A16719)  n-Butylferrocene, 98%   

  • 31904-29-7

  • 10g

  • 469.0CNY

  • Detail
  • Alfa Aesar

  • (A16719)  n-Butylferrocene, 98%   

  • 31904-29-7

  • 50g

  • 1577.0CNY

  • Detail
  • Alfa Aesar

  • (A16719)  n-Butylferrocene, 98%   

  • 31904-29-7

  • 250g

  • 3752.0CNY

  • Detail

31904-29-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 11, 2017

Revision Date: Aug 11, 2017

1.Identification

1.1 GHS Product identifier

Product name Butylferrocene

1.2 Other means of identification

Product number -
Other names 1,1'-di-n-butylferrocene

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:31904-29-7 SDS

31904-29-7Relevant articles and documents

Chemistry via metal atom cocondensation: Isomerization and complexation reactions of organocyclopropanes and spirocycles

Lee Hanlan,Ugolick,Fulcher,Togashi,Bocarsly,Gladysz

, p. 1543 - 1551 (2008/10/08)

Reactions of metal atoms with structurally diverse organocyclopropanes have been studied. Quadricyclane (4) is isomerized to norbornadiene (5) upon cocondensation with a variety of metals, but control experiments suggest this reaction is heterogeneously catalyzed by metal aggregates which form upon warming the matrix. Norcarane (6), 2-norcarene (7), 3-carene (8), and 3-norcarene (9) give no reaction when cocondensed with a broad spectrum of metal atoms, despite the presence of an olefinic group in the latter three. When cyclopropylbenzene (11) is cocondensed with chromium, only bis(cyclopropylbenzene)chromium(0) (12) is formed. However, reaction of iron atoms with spiro[2.4]hepta-4,6-diene (14) yields a 14:64:6:17 ratio of 1,1′-diethylferrocene (15), 1-ethyl-1′-vinylferrocene (16), 1,1′-divinylferrocene (17), and [4]ferrocenophane (18) in 44% yield based upon iron. Cocondensations of iron with spiro[2.4]heptane (20; no reaction) and spiro[4.4]nona-1,3-diene (23; formation of bis(tetrahydroindenyl)iron (24) and 1,2-tetramethylene-1′-butylferrocene (25)) are also reported. Possible mechanisms of spirocycle (14, 23) ring opening and product formation are discussed. No volatile bis(arene)chromium(0) complexes are formed when benzocyclopropene (27) and dispiro[2.2.2.2]deca-4,9-diene (28) are cocondensed with chromium, although the former is polymerized. The preparation of 18 from 1,1′-dilithioferrocene (19) and 1,4-dibromobutane is also described.

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