31928-64-0

Basic information

• Product Name: Silane, (1H-inden-3-yloxy)trimethyl-
• Synonyms: 1-trimethylsiloxy-indan-1-ene;1-trimethylsilyloxy-3H-indene
• CAS NO: 31928-64-0
• Molecular Formula: C12H16OSi
• Molecular Weight: 204.344
• Mol File: 31928-64-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Silane, (1H-inden-3-yloxy)trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, (1H-inden-3-yloxy)trimethyl-(31928-64-0)
• EPA Substance Registry System: Silane, (1H-inden-3-yloxy)trimethyl-(31928-64-0)

Safety Data

• Hazardous Substances Data: 31928-64-0(Hazardous Substances Data)

Upstream product

• 5908-41-8 benzoyltrimethylsilane 
• 107-02-8 acrolein 

Downstream Products

• 111661-88-2 Bis(4-methylphenyl)(1-oxo-2-indanyl)sulfonium-perchlorat 
• 111661-80-4 (1-Oxo-2-indanyl)bis(phenylmethyl)sulfonium-perchlorat 
• 700-76-5 2-fluoroindan-1-one 
• 1579-14-2 2-chloroindanone 
• 697-64-3 (R)-indan-1-ol 
• 192194-67-5 methyl 4-((2,3-dihydro-2-(1H-inden-2-yl)-1-oxo-1H-inden-2-yl)methyl)benzoate 
• 1380445-04-4 (2R,3R,4R,5S)-6-(methylamino)hexane-1,2,3,4,5-pentanol 4-(((1S,2S)-1-hydroxy-2,3-dihydro-1H,1'H-[2,2-biinden]-2-yl)methyl)benzoic acid 

Relevant articles and documents

Ruthenium-Catalyzed Brook Rearrangement Involved Domino Sequence Enabled by Acylsilane-Aldehyde Corporation

A ruthenium-catalyzed [1,2]-Brook rearrangement involved domino sequence is presented to prepare highly functionalized silyloxy indenes with atomic- and step-economy. This domino reaction is triggered by acylsilane-directed C-H activation, and the aldehyde controlled the subsequent enol cyclization/Brook Rearrangement other than β-H elimination. The protocol tolerates a broad substitution pattern, and the further synthetic elaboration of silyloxy indenes allows access to a diverse range of interesting indene and indanone derivatives.