32175-25-0Relevant academic research and scientific papers
Ag(I)-catalyzed addition of cyclopropenones and nitrones to access imides
Xu, Jing-Lei,Tian, Hu,Kang, Jia-Hao,Kang, Wu-Xiang,Sun, Wei,Sun, Rui,Li, Ya-Min,Sun, Meng
, p. 6739 - 6743 (2020)
An unprecedented Ag-catalyzed addition reaction of cyclopropenones and nitrones to access imides was developed. Sequential C-C bond cleavage, N-O bond cleavage, and Mumm rearrangement were uncovered in this process. This protocol exhibited high efficiency, regioselectivity, good yields, and a broad tolerance of various functional groups.
Dendralene synthesis: Rhodium(III)-catalyzed alkenyl C-H activation and coupling reaction with allenyl carbinol carbonate
Wang, Honggen,Beiring, Bernhard,Yu, Da-Gang,Collins, Karl D.,Glorius, Frank
, p. 12430 - 12434 (2013/12/04)
[3]DendrAl(l)ene! A new synthesis of [3]dendralenes is based on a Rh III-catalyzed alkenyl C-H activation and coupling reaction with allenyl carbinol carbonates (see scheme; DG=directing group). A variety of [3]dendralenes with diverse substitution patterns are accessible with good efficiency. The reaction is highly stereoselective and compatible with different directing groups and numerous functional groups. Copyright
