32189-75-6

Upstream product

• 106-95-6 allyl bromide 
• 108-10-1 4-methyl-2-pentanone 
• 556-56-9 allyl iodid 
• 3052-45-7 allyllithium 
• 1730-25-2 allylmagnesium bromide 
• 64549-05-9 allyldibutyltin chloride 
• 111-71-7 heptanal 
• 115345-15-8 allyldioxazaborolidine 
• 15336-98-8 diallyldibutyltin 

Downstream Products

• 19549-77-0 2,4-dimethyl-heptan-4-ol 
• 69036-28-8 (C₄H₉)3SnOC(CH₃)(i-C₄H₉)CH₂CHCH₂ 
• 24850-33-7 allyltributylstanane 

Relevant academic research and scientific papers

A samarium "soluble" anode: A new source of SmI2 reagent for electrosynthetic application

An electrochemical method to prepare solutions of samarium diiodide in THF is reported. The simple electrolysis of a samarium rod provides a rapid and straightforward in situ synthesis of SmI2. The electrogenerated complex catalyzes various C-C bond formations. The reagent is produced continuously (see scheme) and leads to efficient organic electrosynthesis with significantly smaller amounts of solvent than usually required. Copyright

A samarium "soluble" anode: A new source of SmI2 reagent for electrosynthetic application

An electrochemical method to prepare solutions of samarium diiodide in THF is reported. The simple electrolysis of a samarium rod provides a rapid and straightforward in situ synthesis of SmI2. The electrogenerated complex catalyzes various C-C bond formations. The reagent is produced continuously (see scheme) and leads to efficient organic electrosynthesis with significantly smaller amounts of solvent than usually required. Copyright

Tin mediated Barbier type allylation in ionic liquids

The Barbier type allylation of carbonyl compounds is a useful organic transformation as the resultant homoallylic alcohols are important building blocks for many biologically active molecules. Tin mediated Barbier allylation of different carbonyl compounds in room temperature ionic liquid, [BMIM][BF 4] afforded the corresponding homoallylic alcohols in good to excellent yields. The ionic liquid was successfully recycled and reused in allylation reactions.

Allyl transfer to aldehydes and ketones by Bronsted acid activation of allyl and crotyl 1,3,2-dioxazaborolidines

Alkyl dioxazaborolidines are air-stable and often crystalline organoboranes. A variety of Bronsted acids activate allyl dioxazaborolidines to generate reactive allyl-transfer reagents in situ. These reagents add to aldehydes and ketones to generate the corresponding alcohols in good yields under mild conditions. The E- and Z-crotyl reagents react diastereoselectively with aldehydes and ketones to produce anti and syn adducts, respectively, a result consistent with a cyclic transition state (type I mechanism).

SnCl2-mediated carbonyl allylation of aldehydes and ketones in ionic liquid

In ionic liquid [bmim]BF4, SnCl2·2H 2O acts as an inexpensive and efficient metal salt for carbonyl allylation. By applying ionic liquid, some previously reported serious operational problems associated with the SnCl2-mediated allylation reaction are avoided. Furthermore, ketones, which are less reactive than aldehydes, can also be allylated in high yields with this system.

Indium triflate catalyzed allylation of ketones with diallyldibutyltin

A series of ketones underwent an allylation reaction using diallyldibutyltin in the presence of a catalytic amount of In(OTf)3. The method was found to be superior to most of the known methods. Thus, a new allyltin reagent Bu2Sn(allyl)2/In(OTf)3 for ketones was developed.

Alkylvanadium and Alkylniobium Reagents, III. - Two Unconventional Chemical Methods for the Characterisation of Labile Transition Metal Complexes; Application to Allyl Derivatives of V(III), V(V), Cr(III), and Mn(II)

Two little known chemical methods, the "Competition Constant Method" and the production of "Ligand Concentration/ Product Yield Diagrams", are suitable for the characterisation and identification of allyl and crotyl transition metal species prepared in so