322648-74-8

Upstream product

• 3282-30-2 pivaloyl chloride 
• 165524-85-6 6-O-(benzyl)-D-glucal 

Downstream Products

• 322648-75-9 2,2-Dimethyl-propionic acid (2R,3S,4R)-2-benzyloxymethyl-3-triethylsilanyloxy-3,4-dihydro-2H-pyran-4-yl ester 
• 322648-65-7 N-[(2S,3S,4S,5R,6R)-4-((3aS,4R,6S,7R,7aS)-7-Benzyloxy-4-benzyloxymethyl-2-oxo-tetrahydro-[1,3]dioxolo[4,5-c]pyran-6-yloxy)-6-benzyloxymethyl-3-iodo-5-triethylsilanyloxy-tetrahydro-pyran-2-yl]-benzenesulfonamide 
• 322648-64-6 (3aS,4R,6R,7R,7aS)-7-Benzyloxy-4-benzyloxymethyl-6-((2R,3S,4R)-2-benzyloxymethyl-3-triethylsilanyloxy-3,4-dihydro-2H-pyran-4-yloxy)-tetrahydro-[1,3]dioxolo[4,5-c]pyran-2-one 
• 322648-63-5 (3aS,4R,6R,7R,7aR)-4-Benzyloxymethyl-6-((2R,3S,4R)-2-benzyloxymethyl-3-triethylsilanyloxy-3,4-dihydro-2H-pyran-4-yloxy)-7-hydroxy-tetrahydro-[1,3]dioxolo[4,5-c]pyran-2-one 
• 322648-62-4 6-O-benzyl-4-O-TES glucal 

Relevant academic research and scientific papers

Attempts to improve the overall stereoselectivity of the Ireland-Claisen rearrangement

(Chemical Equation Presented) With focus on the steric effects present in the transition states for the [3,3]-sigmatropic rearrangement, the substrate 5 has been designed to improve the overall stereoselectivity of the Ireland-Claisen rearrangement. Exper

Total syntheses of tumor-related antigens N3: Probing the feasibility limits of the glycal assembly method

The total syntheses of two octasaccharide antigens isolated from human milk, 1 and 2, and their corresponding allyl glycosides, 3 and 4, have been achieved by utilizing the glycal method. Convergent assembly of the core hexasaccharides and concurrent intr