95206-93-2Relevant academic research and scientific papers
Reactions of Diene-conjugated 1,3-Dipolar Intermediates: the Formation of Cyclopropaisoquinolines from Benzonitrile o-Alkenylbenzyl Ylides and their Rearrangements to Benzazepines
Motion, Keith R.,Robertson, Ian R.,Sharp, John T.,Walkinshaw, Malcolm D.
, p. 1709 - 1720 (2007/10/02)
The diene-conjugated nitrile ylides 19, generated by 1,3-dehydrochlorination of imidoyl chlorides 18, cyclise at room temperature to give the cyclopropaisoquinolines 21 in a stereospecific reaction.Thermal decomposition of the latter when R1
Reactions of Diene-conjugated 1,3-Dipolar Intermediates: the Formation of Cyclopropisoquinolines from Benzonitrile o-Alkenylbenzyl Ylides and their Rearrangements to 2-Benzazepines
Motion, Keith R.,Robertson, Ian R.,Sharp, John T.
, p. 1531 - 1533 (2007/10/02)
The α,β:γ,δ-unsaturated nitrile ylides (9), when generated by the 1,3-dehydrochlorination of the benzimidoyl chlorides (8) at room temperature, react by a stereospecific 1,1-cycloaddition to give the cyclopropisoquinolines (10); the latter undergo two
