3232-24-4Relevant articles and documents
Method for preparing high-purity 4,4'-oxybisbenzensulfonyl chloride
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Paragraph 0018-0023, (2017/08/28)
The invention discloses a method for preparing high-purity 4,4'-oxybisbenzensulfonyl chloride. The method includes the following steps that (1) concentrated sulfuric acid is dropwise added into diphenyl ether at the temperature of 60 DEG C and the negative pressure, the mixture is fully reacted at the temperature of 130 DEG C to 140 DEG C after the concentrated sulfuric acid is dropwise added, the reaction is completed, and a sulfonic acid mixture is prepared; (2) an organic solvent is added into the sulfonic acid mixture at the temperature of 0 DEG C to 30 DEG C, the pH value of a system is adjusted to be 7 to 9 with alkali, solid-liquid separation is carried out, and diphenyl ether disulfonate is obtained; (3) the diphenyl ether disulfonate is added into acid, the mixture is fully reacted, water is removed after reacting, and a mixed product is obtained; (4) phosphorus oxychloride is dropwise added into the mixed product at the temperature of 80 DEG C or above, the mixture is fully reacted after the temperature of 100 DEG C to 105 DEG C after the phosphorus oxychloride is dropwise added, a reaction product is obtained after reacting, the reaction product is washed, and the 4,4'-oxybisbenzensulfonyl chloride is obtained. OBSC prepared with the method is narrow in melting range, high in purity and whiteness degree and capable of allowing a downstream product foaming agent OBSH to have the advantages of being high in gas-forming amount, narrow in gas-forming temperature range and high in purity and whiteness degree.
The generality of architectural isomerism in designer inclusion frameworks
Holman,Martin,Parker,Ward
, p. 4421 - 4431 (2007/10/03)
We describe herein new structural isomers of a lamellar host system based on organodisulfonate "pillars" that connect opposing hydrogen-bonded sheets, consisting of topologically complementary guanidinium (G) ions and sulfonate (S) groups, to generate inc
SULFUR TRIOXIDE SULFONATION OF DIPHENYL ETHER, DIPHENYL SULFIDE, DIBENZODIOXIN, AND XANTHENE
Cerfontain, Hans,Koeberg-Telder, Ankie,Lindert, Helen C. A. Van,Bakker, Bert H.,Wit, Peter De
, p. 239 - 244 (2007/10/02)
The sulfur trioxide sulfonation of diphenyl ether (1), diphenyl sulfide (2), and the related tricyclic dibenzodioxin (3) and xanthene (4) has been studied.The substrates 1 and 2 both yield initially the 4-sulfonic acid derivative (4-S) and subse