32343-96-7

Basic information

• Product Name: Benzene, [(butylseleno)methyl]-
• CAS NO: 32343-96-7
• Molecular Formula: C11H16Se
• Molecular Weight: 227.208
• Mol File: 32343-96-7.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: Benzene, [(butylseleno)methyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(butylseleno)methyl]-(32343-96-7)
• EPA Substance Registry System: Benzene, [(butylseleno)methyl]-(32343-96-7)

Safety Data

• Hazardous Substances Data: 32343-96-7(Hazardous Substances Data)

Upstream product

• 109-72-8 n-butyllithium 
• 100-39-0 benzyl bromide 
• 100-46-9 benzylamine 
• 20333-40-8 dibutyl diselenide 
• 66310-10-9 N-benzyl-2,4,6-triphenylpyridinium tetrafluoroborate 
• 139623-39-5 5-Benzylselanyl-pentanoic acid 2-thioxo-2H-pyridin-1-yl ester 
• 33979-81-6 butyl tributylstannyl selenide 
• 1092379-04-8 1-butylselanyl-2,2,3,3,4,4,4-heptafluorobutanol 
• 109-65-9 1-bromo-butane 
• 4700-45-2 n-butyl selenocyanate 

Relevant articles and documents

Metal-free synthesis of unsymmetrical selenides from pyridinium salts and diselenides catalysed by visible light

We report the first metal-free selenolations of pyridinium salts with diselenides to prepare unsymmetrical organoselenides catalysed by visible light. This protocol is an efficient and green method for the preparation of unsymmetrical organoselenides because metal-free conditions and readily accessible diselenides are used.

Palladium-catalyzed cross-coupling of PhSeSnBu3 with aryl and alkyl halides in ionic liquids: A practical synthetic method of diorganyl selenides

Palladium-catalyzed cross-coupling reactions of phenyl tributylstannyl selenide with aryl and alkyl halides can proceed smoothly in room temperature ionic liquid, 1-butyl-3-methylimidazolium hexafluorophosphate ([bmim][PF 6]), to give the corresponding diorganyl selenides in good to high yields. The coupling reaction run in [bmim][PF6] has the advantages of rate acceleration and increase of yield in contrast to the reaction run in toluene. Our system not only avoids the use of easily volatile toluene as a solvent but also solves the basic problem of palladium catalyst reuse.

Efficient synthesis of diorganyl selenides via cleavage of Se-Se bond of diselenides by indium(III) catalyst and zinc

A simple and efficient procedure for the synthesis of unsymmetrical diorganyl selenides from an one-pot indium(III) catalyzed procedure, in the presence of zinc, has been developed. Various organic halides and even the unreactive organic chlorides underwe